Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material
Low cost fertilizer industry waste material called carbon slurry, produced in generators of fuel oil based industrial generators was converted into an effective and efficient adsorbent for the removal of hexavalent chromium (VI) from aqueous solutions.The waste was chemically treated, activated, cha...
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| المؤلف الرئيسي: | |
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| مؤلفون آخرون: | , , |
| التنسيق: | article |
| منشور في: |
2009
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| الموضوعات: | |
| الوصول للمادة أونلاين: | https://eprints.kfupm.edu.sa/id/eprint/136168/1/JCIS_in_press.pdf |
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| _version_ | 1864513384573042688 |
|---|---|
| author | K. Gupta, Vinod |
| author2 | Rastogi, Arshi Nayak, Arunima unknown |
| author2_role | author author author |
| author_facet | K. Gupta, Vinod Rastogi, Arshi Nayak, Arunima unknown |
| author_role | author |
| dc.creator.none.fl_str_mv | K. Gupta, Vinod Rastogi, Arshi Nayak, Arunima unknown |
| dc.date.none.fl_str_mv | 2009-09-30 2020 |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | https://eprints.kfupm.edu.sa/id/eprint/136168/1/JCIS_in_press.pdf (2009) Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material. Journal of Colloid and Interface Science. |
| dc.language.none.fl_str_mv | en |
| dc.relation.none.fl_str_mv | https://eprints.kfupm.edu.sa/id/eprint/136168/ |
| dc.rights.*.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Chemistry |
| dc.title.none.fl_str_mv | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material |
| dc.type.none.fl_str_mv | Article PeerReviewed info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | Low cost fertilizer industry waste material called carbon slurry, produced in generators of fuel oil based industrial generators was converted into an effective and efficient adsorbent for the removal of hexavalent chromium (VI) from aqueous solutions.The waste was chemically treated, activated, characterized and used for the adsorption of chromium. The work involves batch experiments to investigate the effect of contact time, pH, temperature, concentration and adsorbent dose on the extent of adsorption by carbon slurry. The maximum adsorption was found at 70 min., 2.0 pH, 4.0 g/L dose, 303 K temperature. Maximum adsorption capacity (15.24 mg/g) of Cr(VI) on carbon slurry was observed at 100 mg/L initial Cr(VI ) concentration. Langmuir and Freundlich adsorption isotherm models were applied to analyze adsorption data, and both were found to be applicable to this adsorption system, in terms of relatively high regression values. Thermodynamic parameters showed that the adsorption of Cr(VI) onto carbon slurry was feasible, spontaneous and exothermic under studied conditions. Kinetics of adsorption was found to follow pseudo second order rate equation. Column studies have been carried out to compare these with the batch capacities. The recovery of Cr(VI) and chemical regeneration of the spent column have also been tried. In all, the results indicated that the adsorbent used in this work proved to be effective material for the treatment of chromium bearing aqueous solutions. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | KFUPM_3591965ea0f50517c9e61b4078486899 |
| identifier_str_mv | (2009) Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material. Journal of Colloid and Interface Science. |
| language_invalid_str_mv | en |
| network_acronym_str | KFUPM |
| network_name_str | King Fahd University of Petroleum and Minerals |
| oai_identifier_str | oai::136168 |
| publishDate | 2009 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste materialK. Gupta, VinodRastogi, ArshiNayak, ArunimaunknownChemistryLow cost fertilizer industry waste material called carbon slurry, produced in generators of fuel oil based industrial generators was converted into an effective and efficient adsorbent for the removal of hexavalent chromium (VI) from aqueous solutions.The waste was chemically treated, activated, characterized and used for the adsorption of chromium. The work involves batch experiments to investigate the effect of contact time, pH, temperature, concentration and adsorbent dose on the extent of adsorption by carbon slurry. The maximum adsorption was found at 70 min., 2.0 pH, 4.0 g/L dose, 303 K temperature. Maximum adsorption capacity (15.24 mg/g) of Cr(VI) on carbon slurry was observed at 100 mg/L initial Cr(VI ) concentration. Langmuir and Freundlich adsorption isotherm models were applied to analyze adsorption data, and both were found to be applicable to this adsorption system, in terms of relatively high regression values. Thermodynamic parameters showed that the adsorption of Cr(VI) onto carbon slurry was feasible, spontaneous and exothermic under studied conditions. Kinetics of adsorption was found to follow pseudo second order rate equation. Column studies have been carried out to compare these with the batch capacities. The recovery of Cr(VI) and chemical regeneration of the spent column have also been tried. In all, the results indicated that the adsorbent used in this work proved to be effective material for the treatment of chromium bearing aqueous solutions.2009-09-302020ArticlePeerReviewedinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://eprints.kfupm.edu.sa/id/eprint/136168/1/JCIS_in_press.pdf (2009) Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material. Journal of Colloid and Interface Science. enhttps://eprints.kfupm.edu.sa/id/eprint/136168/info:eu-repo/semantics/openAccessoai::1361682019-11-01T14:11:19Z |
| spellingShingle | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material K. Gupta, Vinod Chemistry |
| status_str | publishedVersion |
| title | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material |
| title_full | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material |
| title_fullStr | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material |
| title_full_unstemmed | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material |
| title_short | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material |
| title_sort | Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material |
| topic | Chemistry |
| url | https://eprints.kfupm.edu.sa/id/eprint/136168/1/JCIS_in_press.pdf |