Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis
The Cu(I) metal-to-ligand charge-transfer complex, [Cu(dsbtmp)2]+ (dsbtmp = 2,9-di(sec-butyl)-3,4,7,8-tetramethyl-1,10-phenanthroline), exhibits outstanding stability as a visible-light-absorbing photosensitizer in hydrogen-evolving homogeneous photocatalysis. In concert with the Co(dmgH)2(py)Cl wat...
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2013
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| Online Access: | http://hdl.handle.net/10725/6489 http://dx.doi.org/10.1021/ja407816f http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php http://pubs.acs.org/doi/abs/10.1021/ja407816f |
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| _version_ | 1864513480149696512 |
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| author | Khnayzer, Rony S. |
| author2 | McCusker, Catherine E. Olaiya, Babatunde S. Castellano, Felix N. |
| author2_role | author author author |
| author_facet | Khnayzer, Rony S. McCusker, Catherine E. Olaiya, Babatunde S. Castellano, Felix N. |
| author_role | author |
| dc.creator.none.fl_str_mv | Khnayzer, Rony S. McCusker, Catherine E. Olaiya, Babatunde S. Castellano, Felix N. |
| dc.date.none.fl_str_mv | 2013 2017-11-03T07:13:24Z 2017-11-03T07:13:24Z 2017-11-03 |
| dc.identifier.none.fl_str_mv | 0002-7863 http://hdl.handle.net/10725/6489 http://dx.doi.org/10.1021/ja407816f Khnayzer, R. S., McCusker, C. E., Olaiya, B. S., & Castellano, F. N. (2013). Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis. Journal of the American Chemical Society, 135(38), 14068-14070. http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php http://pubs.acs.org/doi/abs/10.1021/ja407816f |
| dc.language.none.fl_str_mv | en |
| dc.relation.none.fl_str_mv | Journal of the American Chemical Society |
| dc.rights.*.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.title.none.fl_str_mv | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | The Cu(I) metal-to-ligand charge-transfer complex, [Cu(dsbtmp)2]+ (dsbtmp = 2,9-di(sec-butyl)-3,4,7,8-tetramethyl-1,10-phenanthroline), exhibits outstanding stability as a visible-light-absorbing photosensitizer in hydrogen-evolving homogeneous photocatalysis. In concert with the Co(dmgH)2(py)Cl water reduction catalyst and N,N-dimethyl-p-toluidine sacrificial donor in 1:1 H2O:CH3CN, this Cu(I) sensitizer remains active even after 5 days of visible-light-pumped (λex = 452 ± 10 nm) hydrogen evolution catalysis. Deuteration studies illustrate that the hydrogen produced from this composition does indeed originate from aqueous protons. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | LAURepo_1b32908939d2ccd9b6f678bdcd37b3e5 |
| identifier_str_mv | 0002-7863 Khnayzer, R. S., McCusker, C. E., Olaiya, B. S., & Castellano, F. N. (2013). Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis. Journal of the American Chemical Society, 135(38), 14068-14070. |
| language_invalid_str_mv | en |
| network_acronym_str | LAURepo |
| network_name_str | Lebanese American University repository |
| oai_identifier_str | oai:laur.lau.edu.lb:10725/6489 |
| publishDate | 2013 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysisKhnayzer, Rony S.McCusker, Catherine E.Olaiya, Babatunde S.Castellano, Felix N.The Cu(I) metal-to-ligand charge-transfer complex, [Cu(dsbtmp)2]+ (dsbtmp = 2,9-di(sec-butyl)-3,4,7,8-tetramethyl-1,10-phenanthroline), exhibits outstanding stability as a visible-light-absorbing photosensitizer in hydrogen-evolving homogeneous photocatalysis. In concert with the Co(dmgH)2(py)Cl water reduction catalyst and N,N-dimethyl-p-toluidine sacrificial donor in 1:1 H2O:CH3CN, this Cu(I) sensitizer remains active even after 5 days of visible-light-pumped (λex = 452 ± 10 nm) hydrogen evolution catalysis. Deuteration studies illustrate that the hydrogen produced from this composition does indeed originate from aqueous protons.PublishedN/A2017-11-03T07:13:24Z2017-11-03T07:13:24Z20132017-11-03Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article0002-7863http://hdl.handle.net/10725/6489http://dx.doi.org/10.1021/ja407816fKhnayzer, R. S., McCusker, C. E., Olaiya, B. S., & Castellano, F. N. (2013). Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis. Journal of the American Chemical Society, 135(38), 14068-14070.http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.phphttp://pubs.acs.org/doi/abs/10.1021/ja407816fenJournal of the American Chemical Societyinfo:eu-repo/semantics/openAccessoai:laur.lau.edu.lb:10725/64892021-03-19T10:03:26Z |
| spellingShingle | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis Khnayzer, Rony S. |
| status_str | publishedVersion |
| title | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis |
| title_full | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis |
| title_fullStr | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis |
| title_full_unstemmed | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis |
| title_short | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis |
| title_sort | Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis |
| url | http://hdl.handle.net/10725/6489 http://dx.doi.org/10.1021/ja407816f http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php http://pubs.acs.org/doi/abs/10.1021/ja407816f |