Robust cuprous phenanthroline sensitizer for solar hydrogen photocatalysis

The Cu(I) metal-to-ligand charge-transfer complex, [Cu(dsbtmp)2]+ (dsbtmp = 2,9-di(sec-butyl)-3,4,7,8-tetramethyl-1,10-phenanthroline), exhibits outstanding stability as a visible-light-absorbing photosensitizer in hydrogen-evolving homogeneous photocatalysis. In concert with the Co(dmgH)2(py)Cl wat...

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Bibliographic Details
Main Author: Khnayzer, Rony S. (author)
Other Authors: McCusker, Catherine E. (author), Olaiya, Babatunde S. (author), Castellano, Felix N. (author)
Format: article
Published: 2013
Online Access:http://hdl.handle.net/10725/6489
http://dx.doi.org/10.1021/ja407816f
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://pubs.acs.org/doi/abs/10.1021/ja407816f
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