Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups
We have synthesized the cyclic Ti9 Keggin trimers [(α-Ti3PW9O38)3(PO4)]18− (1) and [(α-Ti3SiW9O37OH)3(TiO3(OH2)3)]17− (2), which are both composed of three (Ti3XW9O37) units (X = P or Si) linked via three Ti−O−Ti bridges and a capping group, which is either tetrahedral PO4 (1) or octahedral TiO6 (2)...
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2008
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| Online Access: | http://hdl.handle.net/10725/17235 https://doi.org/10.1021/ic801114n http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://pubs.acs.org/doi/full/10.1021/ic801114n |
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| _version_ | 1864513474024964096 |
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| author | Al-Kadamany, Ghada A. |
| author2 | Hussain, Firasat Mal, Sib Sankar Dickman, Michael H. Leclerc-Laronze, Nathalie Marrot, Jérôme Cadot, Emmanuel Kortz, Ulrich |
| author2_role | author author author author author author author |
| author_facet | Al-Kadamany, Ghada A. Hussain, Firasat Mal, Sib Sankar Dickman, Michael H. Leclerc-Laronze, Nathalie Marrot, Jérôme Cadot, Emmanuel Kortz, Ulrich |
| author_role | author |
| dc.creator.none.fl_str_mv | Al-Kadamany, Ghada A. Hussain, Firasat Mal, Sib Sankar Dickman, Michael H. Leclerc-Laronze, Nathalie Marrot, Jérôme Cadot, Emmanuel Kortz, Ulrich |
| dc.date.none.fl_str_mv | 2008 2008-09-10 2025-09-09T13:58:39Z 2025-09-09T13:58:39Z |
| dc.identifier.none.fl_str_mv | 0020-1669 http://hdl.handle.net/10725/17235 https://doi.org/10.1021/ic801114n Al-Kadamany, G. A., Hussain, F., Mal, S. S., Dickman, M. H., Leclerc-Laronze, N., Marrot, J., ... & Kortz, U. (2008). Cyclic Ti9 Keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups. Inorganic chemistry, 47(19), 8574-8576. http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://pubs.acs.org/doi/full/10.1021/ic801114n |
| dc.language.none.fl_str_mv | en |
| dc.relation.none.fl_str_mv | Inorganic Chemistry |
| dc.rights.*.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.title.none.fl_str_mv | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | We have synthesized the cyclic Ti9 Keggin trimers [(α-Ti3PW9O38)3(PO4)]18− (1) and [(α-Ti3SiW9O37OH)3(TiO3(OH2)3)]17− (2), which are both composed of three (Ti3XW9O37) units (X = P or Si) linked via three Ti−O−Ti bridges and a capping group, which is either tetrahedral PO4 (1) or octahedral TiO6 (2). Polyanions 1 and 2 were fully characterized in the solid state (IR, X-ray diffraction, thermogravimetric and elemental analyses) and in solution (31P or 183W NMR). |
| eu_rights_str_mv | openAccess |
| format | article |
| id | LAURepo_4377906bbe5eddf9e45969eabfe5e44c |
| identifier_str_mv | 0020-1669 Al-Kadamany, G. A., Hussain, F., Mal, S. S., Dickman, M. H., Leclerc-Laronze, N., Marrot, J., ... & Kortz, U. (2008). Cyclic Ti9 Keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups. Inorganic chemistry, 47(19), 8574-8576. |
| language_invalid_str_mv | en |
| network_acronym_str | LAURepo |
| network_name_str | Lebanese American University repository |
| oai_identifier_str | oai:laur.lau.edu.lb:10725/17235 |
| publishDate | 2008 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping GroupsAl-Kadamany, Ghada A.Hussain, FirasatMal, Sib SankarDickman, Michael H.Leclerc-Laronze, NathalieMarrot, JérômeCadot, EmmanuelKortz, UlrichWe have synthesized the cyclic Ti9 Keggin trimers [(α-Ti3PW9O38)3(PO4)]18− (1) and [(α-Ti3SiW9O37OH)3(TiO3(OH2)3)]17− (2), which are both composed of three (Ti3XW9O37) units (X = P or Si) linked via three Ti−O−Ti bridges and a capping group, which is either tetrahedral PO4 (1) or octahedral TiO6 (2). Polyanions 1 and 2 were fully characterized in the solid state (IR, X-ray diffraction, thermogravimetric and elemental analyses) and in solution (31P or 183W NMR).Published2025-09-09T13:58:39Z2025-09-09T13:58:39Z20082008-09-10Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article0020-1669http://hdl.handle.net/10725/17235https://doi.org/10.1021/ic801114nAl-Kadamany, G. A., Hussain, F., Mal, S. S., Dickman, M. H., Leclerc-Laronze, N., Marrot, J., ... & Kortz, U. (2008). Cyclic Ti9 Keggin trimers with tetrahedral (PO4) or octahedral (TiO6) capping groups. Inorganic chemistry, 47(19), 8574-8576.http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.phphttps://pubs.acs.org/doi/full/10.1021/ic801114nenInorganic Chemistryinfo:eu-repo/semantics/openAccessoai:laur.lau.edu.lb:10725/172352025-10-23T14:16:40Z |
| spellingShingle | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups Al-Kadamany, Ghada A. |
| status_str | publishedVersion |
| title | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups |
| title_full | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups |
| title_fullStr | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups |
| title_full_unstemmed | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups |
| title_short | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups |
| title_sort | Cyclic Ti9 Keggin Trimers with Tetrahedral (PO4) or Octahedral (TiO6) Capping Groups |
| url | http://hdl.handle.net/10725/17235 https://doi.org/10.1021/ic801114n http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://pubs.acs.org/doi/full/10.1021/ic801114n |