Epoxidation of Alkenes with H2O2 Catalyzed by Dititanium-Containing 19-Tungstodiarsenate(III): Experimental and Theoretical Studies
Epoxidation of a range of alkenes with aqueous H2O2 easily proceeds in the presence of the dititanium-containing 19-tungstodiarsenate(III) [Ti2(OH)2As2W19O67(H2O)]8– (1), which contains five-coordinate Ti atoms. The results of product and kinetics studies support a mechanism that involves a reversib...
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| Other Authors: | , , , , , , , |
| Format: | article |
| Published: |
2010
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| Online Access: | http://hdl.handle.net/10725/17247 https://doi.org/10.1002/ejic.201000615 http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.201000615 |
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| Summary: | Epoxidation of a range of alkenes with aqueous H2O2 easily proceeds in the presence of the dititanium-containing 19-tungstodiarsenate(III) [Ti2(OH)2As2W19O67(H2O)]8– (1), which contains five-coordinate Ti atoms. The results of product and kinetics studies support a mechanism that involves a reversible interaction between H2O2 and the Ti–OH group of 1 to produce a titanium hydroperoxo complex followed by electrophilic oxygen atom transfer from the hydroperoxo ligand to the alkene substrate in the rate-limiting step. The effect of the alkene substrate nature has been investigated at the DFT level. A clear correlation between the energy of πC=C orbitals in the alkene and the turnover frequency values has been found, thereby indicating that the higher nucleophilicity of the alkene, the higher the reactivity. ONIOM (ONIOM = our own n-layered integrated molecular orbital and molecular mechanics) calculations have been employed to evaluate the role of steric effects of alkene substituents. The calculations show that the steric bulk can play a secondary role and tunes the activity in specific cases such as trans-stilbene. |
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