Phosphate removal from aqueous solution using ZVI/sand bed reactor

This research reports on phosphate removal from aqueous solution using ZVI/sand packed columns. The influence of column preconditioning, consisting of ZVI pre-oxidation before feeding the columns with phosphate solution, revealed that a column aged for 1 day was more efficient than un-conditioned co...

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Main Author: Wazne, Mahmoud (author)
Other Authors: Sleiman, Nathalie (author), Deluchat, Veronique (author), Mallet, Martine (author), Courtin-Nomade, Alexandra (author), Kazpard, Veronique (author)
Format: article
Published: 2016
Online Access:http://hdl.handle.net/10725/4000
http://dx.doi.org/10.1016/j.watres.2016.04.054
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://www.sciencedirect.com/science/article/pii/S0043135416302512
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_version_ 1864513462796812288
author Wazne, Mahmoud
author2 Sleiman, Nathalie
Deluchat, Veronique
Mallet, Martine
Courtin-Nomade, Alexandra
Kazpard, Veronique
author2_role author
author
author
author
author
author_facet Wazne, Mahmoud
Sleiman, Nathalie
Deluchat, Veronique
Mallet, Martine
Courtin-Nomade, Alexandra
Kazpard, Veronique
author_role author
dc.creator.none.fl_str_mv Wazne, Mahmoud
Sleiman, Nathalie
Deluchat, Veronique
Mallet, Martine
Courtin-Nomade, Alexandra
Kazpard, Veronique
dc.date.none.fl_str_mv 2016-06-09T11:08:22Z
2016-06-09T11:08:22Z
2016
2016-06-09
dc.identifier.none.fl_str_mv 0043-1354
http://hdl.handle.net/10725/4000
http://dx.doi.org/10.1016/j.watres.2016.04.054
Sleiman, N., Deluchat, V., Wazne, M., Mallet, M., Courtin-Nomade, A., Kazpard, V., & Baudu, M. (2016). Phosphate removal from aqueous solution using ZVI/sand bed reactor: Behavior and mechanism. Water research, 99, 56-65.
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://www.sciencedirect.com/science/article/pii/S0043135416302512
dc.language.none.fl_str_mv en
dc.relation.none.fl_str_mv Water Research
dc.rights.*.fl_str_mv info:eu-repo/semantics/openAccess
dc.title.none.fl_str_mv Phosphate removal from aqueous solution using ZVI/sand bed reactor
behavior and mechanism
dc.type.none.fl_str_mv Article
info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/article
description This research reports on phosphate removal from aqueous solution using ZVI/sand packed columns. The influence of column preconditioning, consisting of ZVI pre-oxidation before feeding the columns with phosphate solution, revealed that a column aged for 1 day was more efficient than un-conditioned column, 5-days and 10-days preconditioned columns. The distribution of phosphate trapped inside the columns was evaluated by measuring phosphate concentration in the solids at different levels (P1, P2 and P3) along the depth of the columns. The distribution of phosphate inside the columns was determined for a time period up to 46 days, corresponding to column saturation. Results showed heterogeneous trapping along the column before saturation and homogeneous distribution upon saturation. The maximum cumulative trapped phosphate after column dismantling was determined before saturation (after 17 days running) at 130, 68 and 31 mgP/gFe at the inlet-P1, P1-P2 and P2-P3 layers, respectively, whereas the homogeneous distribution of phosphate upon saturation was determined at 132 mgP/gFe throughout the column. Solid supports were characterized using SEM, XRD and XPS. Lepidocrocite and maghemite/magnetite were the only iron oxidation products identified at the different layers inside the columns. XPS results confirmed the sorption of phosphate at the surface of ZVI and its oxidation products and highlighted the formation of an iron phosphate complex.
eu_rights_str_mv openAccess
format article
id LAURepo_858121e35ba975a96f8f43979ef9c224
identifier_str_mv 0043-1354
Sleiman, N., Deluchat, V., Wazne, M., Mallet, M., Courtin-Nomade, A., Kazpard, V., & Baudu, M. (2016). Phosphate removal from aqueous solution using ZVI/sand bed reactor: Behavior and mechanism. Water research, 99, 56-65.
language_invalid_str_mv en
network_acronym_str LAURepo
network_name_str Lebanese American University repository
oai_identifier_str oai:laur.lau.edu.lb:10725/4000
publishDate 2016
repository.mail.fl_str_mv
repository.name.fl_str_mv
repository_id_str
spelling Phosphate removal from aqueous solution using ZVI/sand bed reactorbehavior and mechanismWazne, MahmoudSleiman, NathalieDeluchat, VeroniqueMallet, MartineCourtin-Nomade, AlexandraKazpard, VeroniqueThis research reports on phosphate removal from aqueous solution using ZVI/sand packed columns. The influence of column preconditioning, consisting of ZVI pre-oxidation before feeding the columns with phosphate solution, revealed that a column aged for 1 day was more efficient than un-conditioned column, 5-days and 10-days preconditioned columns. The distribution of phosphate trapped inside the columns was evaluated by measuring phosphate concentration in the solids at different levels (P1, P2 and P3) along the depth of the columns. The distribution of phosphate inside the columns was determined for a time period up to 46 days, corresponding to column saturation. Results showed heterogeneous trapping along the column before saturation and homogeneous distribution upon saturation. The maximum cumulative trapped phosphate after column dismantling was determined before saturation (after 17 days running) at 130, 68 and 31 mgP/gFe at the inlet-P1, P1-P2 and P2-P3 layers, respectively, whereas the homogeneous distribution of phosphate upon saturation was determined at 132 mgP/gFe throughout the column. Solid supports were characterized using SEM, XRD and XPS. Lepidocrocite and maghemite/magnetite were the only iron oxidation products identified at the different layers inside the columns. XPS results confirmed the sorption of phosphate at the surface of ZVI and its oxidation products and highlighted the formation of an iron phosphate complex.PublishedN/A2016-06-09T11:08:22Z2016-06-09T11:08:22Z20162016-06-09Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article0043-1354http://hdl.handle.net/10725/4000http://dx.doi.org/10.1016/j.watres.2016.04.054Sleiman, N., Deluchat, V., Wazne, M., Mallet, M., Courtin-Nomade, A., Kazpard, V., & Baudu, M. (2016). Phosphate removal from aqueous solution using ZVI/sand bed reactor: Behavior and mechanism. Water research, 99, 56-65.http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.phphttp://www.sciencedirect.com/science/article/pii/S0043135416302512enWater Researchinfo:eu-repo/semantics/openAccessoai:laur.lau.edu.lb:10725/40002021-03-19T10:03:23Z
spellingShingle Phosphate removal from aqueous solution using ZVI/sand bed reactor
Wazne, Mahmoud
status_str publishedVersion
title Phosphate removal from aqueous solution using ZVI/sand bed reactor
title_full Phosphate removal from aqueous solution using ZVI/sand bed reactor
title_fullStr Phosphate removal from aqueous solution using ZVI/sand bed reactor
title_full_unstemmed Phosphate removal from aqueous solution using ZVI/sand bed reactor
title_short Phosphate removal from aqueous solution using ZVI/sand bed reactor
title_sort Phosphate removal from aqueous solution using ZVI/sand bed reactor
url http://hdl.handle.net/10725/4000
http://dx.doi.org/10.1016/j.watres.2016.04.054
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://www.sciencedirect.com/science/article/pii/S0043135416302512