Unique Catalytic Performance of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8–: The Role of 5-Coordinated Titanium in H2O2 Activation

Unique Catalytic Performance of the Polyoxometalate [Ti2(OH)2As2W19O67(H2O)]8–: The Role of 5-Coordinated Titanium in H2O2 Activation

Tetra-n-butylammonium (TBA) salts of the dititanium sandwich-type 19-tungstodiarsenate(III) [Ti2(OH)2As2W19O67(H2O)]8– (1) revealed a unique catalytic performance in the selective oxidation of organic compounds with aqueous hydrogen peroxide. The selectivity of alkene oxidation strongly depends on t...

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Bibliographic Details
Main Author:	Kholdeeva, Oxana A. (author)
Other Authors:	Donoeva, Baira G. (author), Trubitsina, Tatiana A. (author), Al-Kadamany, Ghada (author), Kortz, Ulrich (author)
Format:	article
Published:	2009
Online Access:	http://hdl.handle.net/10725/17245 https://doi.org/10.1002/ejic.200900608 http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.200900608
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