Upconversion-powered photoelectrochemistry

Upconversion photochemistry occurring between palladium(II) octaethylporphyrin (PdOEP, 1) and 9,10-diphenylanthracene (DPA, 2) in toluene successfully sensitizes nanostructured WO3 photoanodes (Eg = 2.7 eV) to sub-bandgap non-coherent green photons at low power density.

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Bibliographic Details
Main Author: Khnayzer, Rony S. (author)
Other Authors: Blumhoff, Jorg (author), Harrington, Jordan A. (author), Haefele, Alexandre (author), Deng, Fan (author), Castellano, Felix N. (author)
Format: article
Published: 2011
Online Access:http://hdl.handle.net/10725/6520
http://dx.doi.org/10.1039/C1CC16015J
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://pubs.rsc.org/is/content/articlehtml/2012/cc/c1cc16015j
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Summary:Upconversion photochemistry occurring between palladium(II) octaethylporphyrin (PdOEP, 1) and 9,10-diphenylanthracene (DPA, 2) in toluene successfully sensitizes nanostructured WO3 photoanodes (Eg = 2.7 eV) to sub-bandgap non-coherent green photons at low power density.