Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines
We report the preparation and characterization of three pyrimidine-based monomers, specifically: 1-(2-diallylaminoethyl)uracil, 1-(2-diallylaminoethyl)thymine and 1-(2-diallylaminoethyl)cytosine. Monomer synthesis was initiated by reaction of the pyrimidine with ethylene carbonate to form the hydrox...
محفوظ في:
| المؤلف الرئيسي: | |
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| مؤلفون آخرون: | , , , |
| التنسيق: | article |
| منشور في: |
2018
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| الوصول للمادة أونلاين: | http://hdl.handle.net/10725/8397 https://doi.org/10.1080/15685551.2018.1448232 http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://www.tandfonline.com/doi/full/10.1080/15685551.2018.1448232 |
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| _version_ | 1864513484597755904 |
|---|---|
| author | Elaridi, Jomana |
| author2 | Ezzeddine, Alaa Koubeissi, Ali Vladimirov, Nikolay Bouhadir, Kamal H. |
| author2_role | author author author author |
| author_facet | Elaridi, Jomana Ezzeddine, Alaa Koubeissi, Ali Vladimirov, Nikolay Bouhadir, Kamal H. |
| author_role | author |
| dc.creator.none.fl_str_mv | Elaridi, Jomana Ezzeddine, Alaa Koubeissi, Ali Vladimirov, Nikolay Bouhadir, Kamal H. |
| dc.date.none.fl_str_mv | 2018-08-30T11:15:15Z 2018-08-30T11:15:15Z 2018 2018-08-30 |
| dc.identifier.none.fl_str_mv | 1568-5551 http://hdl.handle.net/10725/8397 https://doi.org/10.1080/15685551.2018.1448232 Elaridi, J., Ezzeddine, A., Abramian, L., Koubeissi, A., Vladimirov, N., & Bouhadir, K. H. (2018). Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines. Designed monomers and polymers, 21(1), 64-74. http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://www.tandfonline.com/doi/full/10.1080/15685551.2018.1448232 |
| dc.language.none.fl_str_mv | en |
| dc.relation.none.fl_str_mv | Designed Monomers and Polymers |
| dc.rights.*.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.title.none.fl_str_mv | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | We report the preparation and characterization of three pyrimidine-based monomers, specifically: 1-(2-diallylaminoethyl)uracil, 1-(2-diallylaminoethyl)thymine and 1-(2-diallylaminoethyl)cytosine. Monomer synthesis was initiated by reaction of the pyrimidine with ethylene carbonate to form the hydroxyethyl adduct which was subsequently chlorinated to afford the chloroethyl intermediate. Reaction of the chloroethyl derivatives with diallylamine resulted in the desired monomers. We demonstrated a two-fold increase in the overall yield of the three monomers in comparison to reported procedures. The cyclopolymerization and cyclo-copolymerization of 1-(2-diallylaminoethyl)pyrimidine trifluoroacetate salts in water resulted in low-yield homopolymers. In contrast, the neutral 1-(2-diallylaminoethyl)pyrimidines cyclo-copolymerized with sulfur dioxide and V-50 initiator to yield the corresponding copolymers in higher yields ranging from 30 to 60%. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | LAURepo_bcfc663f38ccb6c5f516ee00e257efb2 |
| identifier_str_mv | 1568-5551 Elaridi, J., Ezzeddine, A., Abramian, L., Koubeissi, A., Vladimirov, N., & Bouhadir, K. H. (2018). Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines. Designed monomers and polymers, 21(1), 64-74. |
| language_invalid_str_mv | en |
| network_acronym_str | LAURepo |
| network_name_str | Lebanese American University repository |
| oai_identifier_str | oai:laur.lau.edu.lb:10725/8397 |
| publishDate | 2018 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidinesElaridi, JomanaEzzeddine, AlaaKoubeissi, AliVladimirov, NikolayBouhadir, Kamal H.We report the preparation and characterization of three pyrimidine-based monomers, specifically: 1-(2-diallylaminoethyl)uracil, 1-(2-diallylaminoethyl)thymine and 1-(2-diallylaminoethyl)cytosine. Monomer synthesis was initiated by reaction of the pyrimidine with ethylene carbonate to form the hydroxyethyl adduct which was subsequently chlorinated to afford the chloroethyl intermediate. Reaction of the chloroethyl derivatives with diallylamine resulted in the desired monomers. We demonstrated a two-fold increase in the overall yield of the three monomers in comparison to reported procedures. The cyclopolymerization and cyclo-copolymerization of 1-(2-diallylaminoethyl)pyrimidine trifluoroacetate salts in water resulted in low-yield homopolymers. In contrast, the neutral 1-(2-diallylaminoethyl)pyrimidines cyclo-copolymerized with sulfur dioxide and V-50 initiator to yield the corresponding copolymers in higher yields ranging from 30 to 60%.PublishedN/A2018-08-30T11:15:15Z2018-08-30T11:15:15Z20182018-08-30Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1568-5551http://hdl.handle.net/10725/8397https://doi.org/10.1080/15685551.2018.1448232Elaridi, J., Ezzeddine, A., Abramian, L., Koubeissi, A., Vladimirov, N., & Bouhadir, K. H. (2018). Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines. Designed monomers and polymers, 21(1), 64-74.http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.phphttps://www.tandfonline.com/doi/full/10.1080/15685551.2018.1448232enDesigned Monomers and Polymersinfo:eu-repo/semantics/openAccessoai:laur.lau.edu.lb:10725/83972021-03-19T10:43:17Z |
| spellingShingle | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines Elaridi, Jomana |
| status_str | publishedVersion |
| title | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines |
| title_full | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines |
| title_fullStr | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines |
| title_full_unstemmed | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines |
| title_short | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines |
| title_sort | Synthesis and polymerization of 1-(2-diallylaminoethyl) pyrimidines |
| url | http://hdl.handle.net/10725/8397 https://doi.org/10.1080/15685551.2018.1448232 http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://www.tandfonline.com/doi/full/10.1080/15685551.2018.1448232 |