Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator

Plants have the ability to develop large mechanical force from chemical energy available with bio-fuels. The energy released by the cleavage of a terminal phosphate ion during the hydrolysis of a bio-fuel assists the transport of ions and fluids in cellular homeostasis. Materials that develop pressu...

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محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Akle, Barbar (author)
مؤلفون آخرون: Leo, Donald J. (author), Sundaresan, Vishnu Baba (author)
التنسيق: conferenceObject
منشور في: 2006
الوصول للمادة أونلاين:http://hdl.handle.net/10725/5691
http://dx.doi.org/10.1117/12.658613
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://proceedings.spiedigitallibrary.org/proceeding.aspx?articleid=1281706
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author Akle, Barbar
author2 Leo, Donald J.
Sundaresan, Vishnu Baba
author2_role author
author
author_facet Akle, Barbar
Leo, Donald J.
Sundaresan, Vishnu Baba
author_role author
dc.creator.none.fl_str_mv Akle, Barbar
Leo, Donald J.
Sundaresan, Vishnu Baba
dc.date.none.fl_str_mv 2006
2017-06-01T06:47:05Z
2017-06-01T06:47:05Z
2017-06-01
dc.identifier.none.fl_str_mv http://hdl.handle.net/10725/5691
http://dx.doi.org/10.1117/12.658613
Sundaresan, V. B., Akle, B., & Leo, D. J. (2006, March). Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator. In Smart Structures and Materials (pp. 61701U-61701U). International Society for Optics and Photonics.
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://proceedings.spiedigitallibrary.org/proceeding.aspx?articleid=1281706
dc.language.none.fl_str_mv en
dc.relation.none.fl_str_mv 6170
dc.rights.*.fl_str_mv info:eu-repo/semantics/openAccess
dc.title.none.fl_str_mv Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
Smart Structures and Materials 2006: Active Materials: Behavior and Mechanics
dc.type.none.fl_str_mv Conference Paper / Proceeding
info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/conferenceObject
description Plants have the ability to develop large mechanical force from chemical energy available with bio-fuels. The energy released by the cleavage of a terminal phosphate ion during the hydrolysis of a bio-fuel assists the transport of ions and fluids in cellular homeostasis. Materials that develop pressure and hence strain similar to the response of plants to an external stimuli are classified as nastic materials. This new class of actuators use protein transporters as functional units to move species and result in deformation [Leo et al 2005 (Proceedings of IMECE - 06)]. The ion transporters are hydrocarbons which are formed across the cellular membranes. The membranes that house the ion transporters are aggregates of phospholipids rigidized by cytoskeleton. Reconstituting these nano-machines on a harder matrix is quintessential to build a functional device. Artificial phospholipid membranes or Biliayer lipid membranes (BLM) have poor structural integrity and do not adhere to most surfaces. Patterned arrays of pores made on Poly-propylene glycol-diacrylate (PPG-DA) substrate, a photo curable polymer was made available to us for initial design iterations for an actuator. Hydrophobicity of PPG-DA posed initial problems to support a BLM. We modified the surface of micropatterned PPG-DA membrane by gold plating it. The surface of the porous PPG-DA membranes was plated with gold (Au). A 10nm seeding layer of Au was sputtered on the surface of the membrane. Further gold was reduced onto the sputtered gold surface [Supriya et al(Langmuir 2004, 20, 8870-8876)] by suspending the samples in a solution of hydroxylamine and Hydrogen tetrachloroaurate(III) trihydrate [HAuCl4.3H2O]. This reduction process increased the thickness of the gold, enhanced its adhesion to the PPG-DA substrate and improved the shapes of the pores. This surface modification of PPG-DA helped us form stable BLM with 1-Palmitoyl-2-Oleoyl-sn-Glycero-3- [Phospho-L-Serine] (Sodium Salt) (POPS), 1-Palmitoyl-2-Oleoyl-sn-Glycero- 3-Phosphoethanolamine (POPE) lipids. The observed ionic resistance of the BLM remained stable and sustained 4 mm water column for the the four hours observation period. This article describes the procedure we adopted to modify the PPG-DA substrate, form a BLM and the procedure to quantify the stability of the BLM formed with -amine and -thiol head groups in the lipids.
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identifier_str_mv Sundaresan, V. B., Akle, B., & Leo, D. J. (2006, March). Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator. In Smart Structures and Materials (pp. 61701U-61701U). International Society for Optics and Photonics.
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spelling Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuatorSmart Structures and Materials 2006: Active Materials: Behavior and MechanicsAkle, BarbarLeo, Donald J.Sundaresan, Vishnu BabaPlants have the ability to develop large mechanical force from chemical energy available with bio-fuels. The energy released by the cleavage of a terminal phosphate ion during the hydrolysis of a bio-fuel assists the transport of ions and fluids in cellular homeostasis. Materials that develop pressure and hence strain similar to the response of plants to an external stimuli are classified as nastic materials. This new class of actuators use protein transporters as functional units to move species and result in deformation [Leo et al 2005 (Proceedings of IMECE - 06)]. The ion transporters are hydrocarbons which are formed across the cellular membranes. The membranes that house the ion transporters are aggregates of phospholipids rigidized by cytoskeleton. Reconstituting these nano-machines on a harder matrix is quintessential to build a functional device. Artificial phospholipid membranes or Biliayer lipid membranes (BLM) have poor structural integrity and do not adhere to most surfaces. Patterned arrays of pores made on Poly-propylene glycol-diacrylate (PPG-DA) substrate, a photo curable polymer was made available to us for initial design iterations for an actuator. Hydrophobicity of PPG-DA posed initial problems to support a BLM. We modified the surface of micropatterned PPG-DA membrane by gold plating it. The surface of the porous PPG-DA membranes was plated with gold (Au). A 10nm seeding layer of Au was sputtered on the surface of the membrane. Further gold was reduced onto the sputtered gold surface [Supriya et al(Langmuir 2004, 20, 8870-8876)] by suspending the samples in a solution of hydroxylamine and Hydrogen tetrachloroaurate(III) trihydrate [HAuCl4.3H2O]. This reduction process increased the thickness of the gold, enhanced its adhesion to the PPG-DA substrate and improved the shapes of the pores. This surface modification of PPG-DA helped us form stable BLM with 1-Palmitoyl-2-Oleoyl-sn-Glycero-3- [Phospho-L-Serine] (Sodium Salt) (POPS), 1-Palmitoyl-2-Oleoyl-sn-Glycero- 3-Phosphoethanolamine (POPE) lipids. The observed ionic resistance of the BLM remained stable and sustained 4 mm water column for the the four hours observation period. This article describes the procedure we adopted to modify the PPG-DA substrate, form a BLM and the procedure to quantify the stability of the BLM formed with -amine and -thiol head groups in the lipids.N/A2017-06-01T06:47:05Z2017-06-01T06:47:05Z20062017-06-01Conference Paper / Proceedinginfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjecthttp://hdl.handle.net/10725/5691http://dx.doi.org/10.1117/12.658613Sundaresan, V. B., Akle, B., & Leo, D. J. (2006, March). Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator. In Smart Structures and Materials (pp. 61701U-61701U). International Society for Optics and Photonics.http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.phphttp://proceedings.spiedigitallibrary.org/proceeding.aspx?articleid=1281706en6170info:eu-repo/semantics/openAccessoai:laur.lau.edu.lb:10725/56912021-03-19T10:00:54Z
spellingShingle Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
Akle, Barbar
status_str publishedVersion
title Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
title_full Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
title_fullStr Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
title_full_unstemmed Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
title_short Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
title_sort Investigation on micro-patterned gold-plated polymer substrate for a micro hydraulic actuator
url http://hdl.handle.net/10725/5691
http://dx.doi.org/10.1117/12.658613
http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php
http://proceedings.spiedigitallibrary.org/proceeding.aspx?articleid=1281706