Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide
This paper describes the fabrication of multifunctional electronic textiles (e-textiles) capable of simultaneous detection and uptake of hydrogen sulfide (H2S). Hydrothermal templation of the bismuth-based framework (Bi(HHTP)) onto the textile installs a conductive coating from the molecular buildin...
محفوظ في:
| المؤلف الرئيسي: | |
|---|---|
| مؤلفون آخرون: | , , , , , , , |
| التنسيق: | article |
| منشور في: |
2025
|
| الوصول للمادة أونلاين: | http://hdl.handle.net/10725/17255 https://doi.org/10.1002/anie.202509883 http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202509883 |
| الوسوم: |
إضافة وسم
لا توجد وسوم, كن أول من يضع وسما على هذه التسجيلة!
|
| _version_ | 1864513474305982464 |
|---|---|
| author | Cline, Evan L. |
| author2 | Obeso, Juan L. Al-Kadamany, Ghada Gutiérrez-Alejandre, Aída Kanaly, Peyton Noh, Hyuk-Jun Ambrogi, Emma J. Flores, Gabriel Blount, Brandon |
| author2_role | author author author author author author author author |
| author_facet | Cline, Evan L. Obeso, Juan L. Al-Kadamany, Ghada Gutiérrez-Alejandre, Aída Kanaly, Peyton Noh, Hyuk-Jun Ambrogi, Emma J. Flores, Gabriel Blount, Brandon |
| author_role | author |
| dc.creator.none.fl_str_mv | Cline, Evan L. Obeso, Juan L. Al-Kadamany, Ghada Gutiérrez-Alejandre, Aída Kanaly, Peyton Noh, Hyuk-Jun Ambrogi, Emma J. Flores, Gabriel Blount, Brandon |
| dc.date.none.fl_str_mv | 2025-09-15T07:06:14Z 2025-09-15T07:06:14Z 2025 2025-08-26 |
| dc.identifier.none.fl_str_mv | 1433-7851 http://hdl.handle.net/10725/17255 https://doi.org/10.1002/anie.202509883 Cline, E. L., Obeso, J. L., Al‐Kadamany, G., Gutiérrez‐Alejandre, A., Kanaly, P., Noh, H. J., ... & Mirica, K. A. (2025). Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide. Angewandte Chemie International Edition, e202509883. http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202509883 |
| dc.language.none.fl_str_mv | en |
| dc.relation.none.fl_str_mv | Angewandte Chemie International Edition |
| dc.rights.*.fl_str_mv | info:eu-repo/semantics/openAccess |
| dc.title.none.fl_str_mv | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide |
| dc.type.none.fl_str_mv | Article info:eu-repo/semantics/publishedVersion info:eu-repo/semantics/article |
| description | This paper describes the fabrication of multifunctional electronic textiles (e-textiles) capable of simultaneous detection and uptake of hydrogen sulfide (H2S). Hydrothermal templation of the bismuth-based framework (Bi(HHTP)) onto the textile installs a conductive coating from the molecular building blocks of 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and bismuth acetate. Electronic textile (e-textile) surfaces achieve average Bi(HHTP) loadings of 8 ± 2 mg cm−2, corresponding to 20% ± 4% of the e-textile being Bi(HHTP) by mass, and demonstrate average resistivities of 1.26 kΩ cm−1 with good stability to withstand mechanical stressors. The resulting e-textiles exhibit an analyte-selective, concentration-dependent chemiresistive response to H2S from 80 to 5 ppm, with good selectivity toward H2S over SO2, NO, NO2, NH3, and CO. The materials reach micro-breakthrough capacities of up to 16.8 and 14.8 mmol g−1 under exposure to 4.6% H2S, for e-textile and bulk powder, respectively. Spectroscopic analysis suggests that material–analyte interactions are characterized by the formation of polysulfide species. The resulting electronic textile represents a novel approach toward the development of smart membranes capable of simultaneous sensing and filtration of H2S. |
| eu_rights_str_mv | openAccess |
| format | article |
| id | LAURepo_fb534d3a3af844ace4be975f9da1110c |
| identifier_str_mv | 1433-7851 Cline, E. L., Obeso, J. L., Al‐Kadamany, G., Gutiérrez‐Alejandre, A., Kanaly, P., Noh, H. J., ... & Mirica, K. A. (2025). Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide. Angewandte Chemie International Edition, e202509883. |
| language_invalid_str_mv | en |
| network_acronym_str | LAURepo |
| network_name_str | Lebanese American University repository |
| oai_identifier_str | oai:laur.lau.edu.lb:10725/17255 |
| publishDate | 2025 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| spelling | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen SulfideCline, Evan L.Obeso, Juan L.Al-Kadamany, GhadaGutiérrez-Alejandre, AídaKanaly, PeytonNoh, Hyuk-JunAmbrogi, Emma J.Flores, GabrielBlount, BrandonThis paper describes the fabrication of multifunctional electronic textiles (e-textiles) capable of simultaneous detection and uptake of hydrogen sulfide (H2S). Hydrothermal templation of the bismuth-based framework (Bi(HHTP)) onto the textile installs a conductive coating from the molecular building blocks of 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and bismuth acetate. Electronic textile (e-textile) surfaces achieve average Bi(HHTP) loadings of 8 ± 2 mg cm−2, corresponding to 20% ± 4% of the e-textile being Bi(HHTP) by mass, and demonstrate average resistivities of 1.26 kΩ cm−1 with good stability to withstand mechanical stressors. The resulting e-textiles exhibit an analyte-selective, concentration-dependent chemiresistive response to H2S from 80 to 5 ppm, with good selectivity toward H2S over SO2, NO, NO2, NH3, and CO. The materials reach micro-breakthrough capacities of up to 16.8 and 14.8 mmol g−1 under exposure to 4.6% H2S, for e-textile and bulk powder, respectively. Spectroscopic analysis suggests that material–analyte interactions are characterized by the formation of polysulfide species. The resulting electronic textile represents a novel approach toward the development of smart membranes capable of simultaneous sensing and filtration of H2S.Published2025-09-15T07:06:14Z2025-09-15T07:06:14Z20252025-08-26Articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1433-7851http://hdl.handle.net/10725/17255https://doi.org/10.1002/anie.202509883Cline, E. L., Obeso, J. L., Al‐Kadamany, G., Gutiérrez‐Alejandre, A., Kanaly, P., Noh, H. J., ... & Mirica, K. A. (2025). Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide. Angewandte Chemie International Edition, e202509883.http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.phphttps://onlinelibrary.wiley.com/doi/full/10.1002/anie.202509883enAngewandte Chemie International Editioninfo:eu-repo/semantics/openAccessoai:laur.lau.edu.lb:10725/172552025-10-23T14:11:20Z |
| spellingShingle | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide Cline, Evan L. |
| status_str | publishedVersion |
| title | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide |
| title_full | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide |
| title_fullStr | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide |
| title_full_unstemmed | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide |
| title_short | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide |
| title_sort | Multifunctional Electronic Textiles for the Simultaneous Detection and Uptake of Hydrogen Sulfide |
| url | http://hdl.handle.net/10725/17255 https://doi.org/10.1002/anie.202509883 http://libraries.lau.edu.lb/research/laur/terms-of-use/articles.php https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202509883 |