Reduced graphene aerogels as energy efficient selective oil sorbents
<p dir="ltr">Graphene aerogels are widely used in the oil–water system as they possess high internal surface area and super-oleophilic properties. However, they tend to absorb water along with oil, and to overcome this problem; surface coatings are generally employed using expensive...
محفوظ في:
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| مؤلفون آخرون: | , , , |
| منشور في: |
2022
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| الملخص: | <p dir="ltr">Graphene aerogels are widely used in the oil–water system as they possess high internal surface area and super-oleophilic properties. However, they tend to absorb water along with oil, and to overcome this problem; surface coatings are generally employed using expensive fluoro-silane compounds. It leads to an increase in production costs and environmental concerns. Herein, we report super-hydrophobic 3D graphene aerogels as selective oil sorbent for oil–water separation. The reduction of oxygen-containing functional groups on the surface of graphene aerogels has been studied and characterized with FTIR. The thermal treatment of up to 700 °C was carried out using an in-house flow system. The gases used to reduce graphene oxide aerogel are H<sub>2</sub> and N<sub>2</sub> with an optimized ratio of 5:95. The presence of H<sub>2</sub> significantly decreased the oxygen-containing functional groups in graphene aerogel. The increase in the C/O ratio results in higher uptake capacity due to higher surface area and pore volume. The thermal reduction yields a C/O ratio of 24:1, slightly higher than most reported values.</p><h2>Other Information</h2><p dir="ltr">Published in: Energy Reports<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.egyr.2022.10.076" target="_blank">https://dx.doi.org/10.1016/j.egyr.2022.10.076</a></p> |
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