Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode
<p dir="ltr">At high concentration or in the presence of electrolytes and organic solvents, solutions of cellulose nanocrystals (CNCs) can form gels exhibiting optical properties similar to the ones of liquid crystal phases. In an attempt to pattern such a gel phase, we have studied...
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2014
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| _version_ | 1864513506628337664 |
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| author | Jean-Michel Daignan (572645) |
| author2 | Ran Chen (1233813) Khaled A. Mahmoud (14634483) Yuan Ma (189824) IIan G. Hill (19503514) Laurent Kreplak (258828) |
| author2_role | author author author author author |
| author_facet | Jean-Michel Daignan (572645) Ran Chen (1233813) Khaled A. Mahmoud (14634483) Yuan Ma (189824) IIan G. Hill (19503514) Laurent Kreplak (258828) |
| author_role | author |
| dc.creator.none.fl_str_mv | Jean-Michel Daignan (572645) Ran Chen (1233813) Khaled A. Mahmoud (14634483) Yuan Ma (189824) IIan G. Hill (19503514) Laurent Kreplak (258828) |
| dc.date.none.fl_str_mv | 2014-06-04T06:00:00Z |
| dc.identifier.none.fl_str_mv | 10.1371/journal.pone.0099202 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/Patterning_of_Nanocrystalline_Cellulose_Gel_Phase_by_Electrodissolution_of_a_Metallic_Electrode/26868283 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Engineering Materials engineering Nanotechnology Resources engineering and extractive metallurgy Electrode potentials Silver Cellulose Copper Iron Nanocrystals Radii Suspensions |
| dc.title.none.fl_str_mv | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p dir="ltr">At high concentration or in the presence of electrolytes and organic solvents, solutions of cellulose nanocrystals (CNCs) can form gels exhibiting optical properties similar to the ones of liquid crystal phases. In an attempt to pattern such a gel phase, we have studied the electrodissolution of a metallic electrode in a water suspension of carboxylated CNCs (cCNCs). Depending on the metal used, the electrodissolution process was observed at a different positive potential. In the case of copper the minimum potential at which we could observe optically the growth of the gel phase was 200 mV. The growth rate was current limited indicating that the process was controlled by the electrodissolution of the copper electrode. This hypothesis was confirmed by using circular and square copper patterns as positive electrodes. In both cases, the consumption of the electrode material was observed optically and correlated with the growth of the gel phase.</p><h2>Other Information</h2><p dir="ltr">Published in: PLOS ONE<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://doi.org/10.1371/journal.pone.0099202" target="_blank">https://doi.org/10.1371/journal.pone.0099202</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_0a97abd5691c7789923451f109514b7c |
| identifier_str_mv | 10.1371/journal.pone.0099202 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/26868283 |
| publishDate | 2014 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic ElectrodeJean-Michel Daignan (572645)Ran Chen (1233813)Khaled A. Mahmoud (14634483)Yuan Ma (189824)IIan G. Hill (19503514)Laurent Kreplak (258828)EngineeringMaterials engineeringNanotechnologyResources engineering and extractive metallurgyElectrode potentialsSilverCelluloseCopperIronNanocrystalsRadiiSuspensions<p dir="ltr">At high concentration or in the presence of electrolytes and organic solvents, solutions of cellulose nanocrystals (CNCs) can form gels exhibiting optical properties similar to the ones of liquid crystal phases. In an attempt to pattern such a gel phase, we have studied the electrodissolution of a metallic electrode in a water suspension of carboxylated CNCs (cCNCs). Depending on the metal used, the electrodissolution process was observed at a different positive potential. In the case of copper the minimum potential at which we could observe optically the growth of the gel phase was 200 mV. The growth rate was current limited indicating that the process was controlled by the electrodissolution of the copper electrode. This hypothesis was confirmed by using circular and square copper patterns as positive electrodes. In both cases, the consumption of the electrode material was observed optically and correlated with the growth of the gel phase.</p><h2>Other Information</h2><p dir="ltr">Published in: PLOS ONE<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://doi.org/10.1371/journal.pone.0099202" target="_blank">https://doi.org/10.1371/journal.pone.0099202</a></p>2014-06-04T06:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1371/journal.pone.0099202https://figshare.com/articles/journal_contribution/Patterning_of_Nanocrystalline_Cellulose_Gel_Phase_by_Electrodissolution_of_a_Metallic_Electrode/26868283CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/268682832014-06-04T06:00:00Z |
| spellingShingle | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode Jean-Michel Daignan (572645) Engineering Materials engineering Nanotechnology Resources engineering and extractive metallurgy Electrode potentials Silver Cellulose Copper Iron Nanocrystals Radii Suspensions |
| status_str | publishedVersion |
| title | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode |
| title_full | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode |
| title_fullStr | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode |
| title_full_unstemmed | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode |
| title_short | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode |
| title_sort | Patterning of Nanocrystalline Cellulose Gel Phase by Electrodissolution of a Metallic Electrode |
| topic | Engineering Materials engineering Nanotechnology Resources engineering and extractive metallurgy Electrode potentials Silver Cellulose Copper Iron Nanocrystals Radii Suspensions |