Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application

<p dir="ltr">For practical uses, there has been a lot of interest in simple, inexpensive, and efficient synthesis of materials for supercapacitor applications. Pure and cobalt-doped zinc sulfide (Co-doped ZnS) powder samples were synthesized in this study using a straightforward co-p...

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Main Author: Emmanuel Tom (6751298) (author)
Other Authors: Abhijai Velluva (22224997) (author), Anit Joseph (22225000) (author), Tiju Thomas (1698421) (author), Mizaj Shabil Sha (17714286) (author), P. V Jithin (22225003) (author), Deepu Thomas (22225006) (author), Kishor Kumar Sadasivuni (8036039) (author), Joji Kurian (1618291) (author)
Published: 2024
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author Emmanuel Tom (6751298)
author2 Abhijai Velluva (22224997)
Anit Joseph (22225000)
Tiju Thomas (1698421)
Mizaj Shabil Sha (17714286)
P. V Jithin (22225003)
Deepu Thomas (22225006)
Kishor Kumar Sadasivuni (8036039)
Joji Kurian (1618291)
author2_role author
author
author
author
author
author
author
author
author_facet Emmanuel Tom (6751298)
Abhijai Velluva (22224997)
Anit Joseph (22225000)
Tiju Thomas (1698421)
Mizaj Shabil Sha (17714286)
P. V Jithin (22225003)
Deepu Thomas (22225006)
Kishor Kumar Sadasivuni (8036039)
Joji Kurian (1618291)
author_role author
dc.creator.none.fl_str_mv Emmanuel Tom (6751298)
Abhijai Velluva (22224997)
Anit Joseph (22225000)
Tiju Thomas (1698421)
Mizaj Shabil Sha (17714286)
P. V Jithin (22225003)
Deepu Thomas (22225006)
Kishor Kumar Sadasivuni (8036039)
Joji Kurian (1618291)
dc.date.none.fl_str_mv 2024-11-01T00:00:00Z
dc.identifier.none.fl_str_mv 10.1007/s11664-024-11535-6
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Tailoring_the_Electrochemical_Properties_of_ZnS_Electrodes_via_Cobalt_Doping_for_Improved_Supercapacitor_Application/30094939
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Chemical sciences
Physical chemistry
Engineering
Materials engineering
Nanotechnology
Co-doped
ZnS
supercapacitor
capacitance
dc.title.none.fl_str_mv Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p dir="ltr">For practical uses, there has been a lot of interest in simple, inexpensive, and efficient synthesis of materials for supercapacitor applications. Pure and cobalt-doped zinc sulfide (Co-doped ZnS) powder samples were synthesized in this study using a straightforward co-precipitation process, and their electrochemical performance was examined. It was observed that, at a scan rate of 10 mV s<sup>−1</sup>, pure ZnS has a specific capacitance of only 460.7 F g<sup>−1</sup>; however, the Co-doping in ZnS increases it to 947.8 F g−1 for the 5% Co-doped sample, Co (0.05): ZnS. The results suggest that Co-doping in ZnS increases the kinetics and rate of redox processes. The increase in electrochemical active sites brought about by integrating Co into ZnS increases the surface area and results in the sample's capacity for storage. The encouraging findings increase the likelihood of elemental doping with other transition metal elements to increase the energy storage capability of earth-abundant ZnS samples.</p><h2>Other Information</h2><p dir="ltr">Published in: Journal of Electronic Materials<br>License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1007/s11664-024-11535-6" target="_blank">https://dx.doi.org/10.1007/s11664-024-11535-6</a></p>
eu_rights_str_mv openAccess
id Manara2_1399ceef03876ea281e2da3f8d0e9ab5
identifier_str_mv 10.1007/s11664-024-11535-6
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/30094939
publishDate 2024
repository.mail.fl_str_mv
repository.name.fl_str_mv
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rights_invalid_str_mv CC BY 4.0
spelling Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor ApplicationEmmanuel Tom (6751298)Abhijai Velluva (22224997)Anit Joseph (22225000)Tiju Thomas (1698421)Mizaj Shabil Sha (17714286)P. V Jithin (22225003)Deepu Thomas (22225006)Kishor Kumar Sadasivuni (8036039)Joji Kurian (1618291)Chemical sciencesPhysical chemistryEngineeringMaterials engineeringNanotechnologyCo-dopedZnSsupercapacitorcapacitance<p dir="ltr">For practical uses, there has been a lot of interest in simple, inexpensive, and efficient synthesis of materials for supercapacitor applications. Pure and cobalt-doped zinc sulfide (Co-doped ZnS) powder samples were synthesized in this study using a straightforward co-precipitation process, and their electrochemical performance was examined. It was observed that, at a scan rate of 10 mV s<sup>−1</sup>, pure ZnS has a specific capacitance of only 460.7 F g<sup>−1</sup>; however, the Co-doping in ZnS increases it to 947.8 F g−1 for the 5% Co-doped sample, Co (0.05): ZnS. The results suggest that Co-doping in ZnS increases the kinetics and rate of redox processes. The increase in electrochemical active sites brought about by integrating Co into ZnS increases the surface area and results in the sample's capacity for storage. The encouraging findings increase the likelihood of elemental doping with other transition metal elements to increase the energy storage capability of earth-abundant ZnS samples.</p><h2>Other Information</h2><p dir="ltr">Published in: Journal of Electronic Materials<br>License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1007/s11664-024-11535-6" target="_blank">https://dx.doi.org/10.1007/s11664-024-11535-6</a></p>2024-11-01T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1007/s11664-024-11535-6https://figshare.com/articles/journal_contribution/Tailoring_the_Electrochemical_Properties_of_ZnS_Electrodes_via_Cobalt_Doping_for_Improved_Supercapacitor_Application/30094939CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/300949392024-11-01T00:00:00Z
spellingShingle Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
Emmanuel Tom (6751298)
Chemical sciences
Physical chemistry
Engineering
Materials engineering
Nanotechnology
Co-doped
ZnS
supercapacitor
capacitance
status_str publishedVersion
title Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
title_full Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
title_fullStr Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
title_full_unstemmed Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
title_short Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
title_sort Tailoring the Electrochemical Properties of ZnS Electrodes via Cobalt Doping for Improved Supercapacitor Application
topic Chemical sciences
Physical chemistry
Engineering
Materials engineering
Nanotechnology
Co-doped
ZnS
supercapacitor
capacitance