A Novel Green Synthesis of Thalidomide and Analogs

<p dir="ltr">Thalidomide and its derivatives are currently under investigation for their antiangiogenic, immunomodulative, and anticancer properties. Current methods used to synthesize these compounds involve multiple steps and extensive workup procedures. Described herein is an effi...

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Main Author: Ellis Benjamin (18891907) (author)
Other Authors: Yousef M. Hijji (3058938) (author)
Published: 2017
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author Ellis Benjamin (18891907)
author2 Yousef M. Hijji (3058938)
author2_role author
author_facet Ellis Benjamin (18891907)
Yousef M. Hijji (3058938)
author_role author
dc.creator.none.fl_str_mv Ellis Benjamin (18891907)
Yousef M. Hijji (3058938)
dc.date.none.fl_str_mv 2017-02-20T09:00:00Z
dc.identifier.none.fl_str_mv 10.1155/2017/6436185
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/A_Novel_Green_Synthesis_of_Thalidomide_and_Analogs/26114746
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Biomedical and clinical sciences
Pharmacology and pharmaceutical sciences
Chemical sciences
Medicinal and biomolecular chemistry
Antiangiogenic
Crohn's disease
Neurodegenerative disorders
Teratogenic effects
dc.title.none.fl_str_mv A Novel Green Synthesis of Thalidomide and Analogs
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p dir="ltr">Thalidomide and its derivatives are currently under investigation for their antiangiogenic, immunomodulative, and anticancer properties. Current methods used to synthesize these compounds involve multiple steps and extensive workup procedures. Described herein is an efficient microwave irradiation green synthesis method that allows preparation of thalidomide and its analogs in a one-pot multicomponent synthesis system. The multicomponent synthesis system developed involves an array of cyclic anhydrides, glutamic acid, and ammonium chloride in the presence of catalytic amounts of 4-N,N-dimethylaminopyridine (DMAP) to produce thalidomide and structurally related compounds within minutes in good isolated yields.</p><h2>Other Information</h2><p dir="ltr">Published in: Journal of Chemistry<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1155/2017/6436185" target="_blank">https://dx.doi.org/10.1155/2017/6436185</a></p>
eu_rights_str_mv openAccess
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identifier_str_mv 10.1155/2017/6436185
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/26114746
publishDate 2017
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rights_invalid_str_mv CC BY 4.0
spelling A Novel Green Synthesis of Thalidomide and AnalogsEllis Benjamin (18891907)Yousef M. Hijji (3058938)Biomedical and clinical sciencesPharmacology and pharmaceutical sciencesChemical sciencesMedicinal and biomolecular chemistryAntiangiogenicCrohn's diseaseNeurodegenerative disordersTeratogenic effects<p dir="ltr">Thalidomide and its derivatives are currently under investigation for their antiangiogenic, immunomodulative, and anticancer properties. Current methods used to synthesize these compounds involve multiple steps and extensive workup procedures. Described herein is an efficient microwave irradiation green synthesis method that allows preparation of thalidomide and its analogs in a one-pot multicomponent synthesis system. The multicomponent synthesis system developed involves an array of cyclic anhydrides, glutamic acid, and ammonium chloride in the presence of catalytic amounts of 4-N,N-dimethylaminopyridine (DMAP) to produce thalidomide and structurally related compounds within minutes in good isolated yields.</p><h2>Other Information</h2><p dir="ltr">Published in: Journal of Chemistry<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1155/2017/6436185" target="_blank">https://dx.doi.org/10.1155/2017/6436185</a></p>2017-02-20T09:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1155/2017/6436185https://figshare.com/articles/journal_contribution/A_Novel_Green_Synthesis_of_Thalidomide_and_Analogs/26114746CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/261147462017-02-20T09:00:00Z
spellingShingle A Novel Green Synthesis of Thalidomide and Analogs
Ellis Benjamin (18891907)
Biomedical and clinical sciences
Pharmacology and pharmaceutical sciences
Chemical sciences
Medicinal and biomolecular chemistry
Antiangiogenic
Crohn's disease
Neurodegenerative disorders
Teratogenic effects
status_str publishedVersion
title A Novel Green Synthesis of Thalidomide and Analogs
title_full A Novel Green Synthesis of Thalidomide and Analogs
title_fullStr A Novel Green Synthesis of Thalidomide and Analogs
title_full_unstemmed A Novel Green Synthesis of Thalidomide and Analogs
title_short A Novel Green Synthesis of Thalidomide and Analogs
title_sort A Novel Green Synthesis of Thalidomide and Analogs
topic Biomedical and clinical sciences
Pharmacology and pharmaceutical sciences
Chemical sciences
Medicinal and biomolecular chemistry
Antiangiogenic
Crohn's disease
Neurodegenerative disorders
Teratogenic effects