In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals
<p dir="ltr">An efficient multi-functional electrolyzer with a Ni- and Fe-layered double hydroxide (NiFe-LDH) anode and a binary NiMo cathode is designed for overall water splitting coupled with the desalination of saline water and production of value-added chemicals. The NiFe-LDH an...
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| المؤلف الرئيسي: | |
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| مؤلفون آخرون: | , , |
| منشور في: |
2023
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| الموضوعات: | |
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إضافة وسم
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| _version_ | 1864513529511411712 |
|---|---|
| author | Byeong-ju Kim (7320773) |
| author2 | Ho Kyong Shon (2092561) Dong Suk Han (1748989) Hyunwoong Park (1521754) |
| author2_role | author author author |
| author_facet | Byeong-ju Kim (7320773) Ho Kyong Shon (2092561) Dong Suk Han (1748989) Hyunwoong Park (1521754) |
| author_role | author |
| dc.creator.none.fl_str_mv | Byeong-ju Kim (7320773) Ho Kyong Shon (2092561) Dong Suk Han (1748989) Hyunwoong Park (1521754) |
| dc.date.none.fl_str_mv | 2023-04-01T00:00:00Z |
| dc.identifier.none.fl_str_mv | 10.1016/j.desal.2023.116431 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/In-situ_desalination-coupled_electrolysis_with_concurrent_one-step-synthesis_of_value-added_chemicals/25036427 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Chemical sciences Physical chemistry Engineering Chemical engineering Materials engineering Desalination Bipolar membrane Electrocatalysis Seawater electrolysis Acid and base |
| dc.title.none.fl_str_mv | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p dir="ltr">An efficient multi-functional electrolyzer with a Ni- and Fe-layered double hydroxide (NiFe-LDH) anode and a binary NiMo cathode is designed for overall water splitting coupled with the desalination of saline water and production of value-added chemicals. The NiFe-LDH and NiMo pairs separated by a bipolar membrane (BPM) show overpotentials as low as those of noble metal catalysts for oxygen and hydrogen evolution reactions in 1 M KOH and 1 M H<sub>2</sub>SO<sub>4</sub> solutions, respectively. Arraying anion and cation-exchange membranes (AEMs and CEMs, respectively) with BPMs (NiFe-LDH/BPM/[AEM/CEM] n /BPM/NiMo; n = 1 or 5) further enables the desalination of brackish water and seawater at specific energy consumption of 1.8 kWh m<sup>−3</sup>, with concurrent production of HCl and NaOH. The Faradaic efficiencies of the device for O<sub>2</sub> and H<sub>2</sub> production are >95 % at J = 100 mA cm<sup>−2</sup> over 20 h, while the initial pH values of the anolyte and catholyte remain unchanged. Detailed surface characterization of the electrocatalysts is performed, and various electrolyzer configurations are compared in terms of desalination efficiency.</p><h2>Other Information</h2><p dir="ltr">Published in: Desalination<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.desal.2023.116431" target="_blank">https://dx.doi.org/10.1016/j.desal.2023.116431</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_2a439fec75b9b65a9a6f7ef0f8ac456f |
| identifier_str_mv | 10.1016/j.desal.2023.116431 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/25036427 |
| publishDate | 2023 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicalsByeong-ju Kim (7320773)Ho Kyong Shon (2092561)Dong Suk Han (1748989)Hyunwoong Park (1521754)Chemical sciencesPhysical chemistryEngineeringChemical engineeringMaterials engineeringDesalinationBipolar membraneElectrocatalysisSeawater electrolysisAcid and base<p dir="ltr">An efficient multi-functional electrolyzer with a Ni- and Fe-layered double hydroxide (NiFe-LDH) anode and a binary NiMo cathode is designed for overall water splitting coupled with the desalination of saline water and production of value-added chemicals. The NiFe-LDH and NiMo pairs separated by a bipolar membrane (BPM) show overpotentials as low as those of noble metal catalysts for oxygen and hydrogen evolution reactions in 1 M KOH and 1 M H<sub>2</sub>SO<sub>4</sub> solutions, respectively. Arraying anion and cation-exchange membranes (AEMs and CEMs, respectively) with BPMs (NiFe-LDH/BPM/[AEM/CEM] n /BPM/NiMo; n = 1 or 5) further enables the desalination of brackish water and seawater at specific energy consumption of 1.8 kWh m<sup>−3</sup>, with concurrent production of HCl and NaOH. The Faradaic efficiencies of the device for O<sub>2</sub> and H<sub>2</sub> production are >95 % at J = 100 mA cm<sup>−2</sup> over 20 h, while the initial pH values of the anolyte and catholyte remain unchanged. Detailed surface characterization of the electrocatalysts is performed, and various electrolyzer configurations are compared in terms of desalination efficiency.</p><h2>Other Information</h2><p dir="ltr">Published in: Desalination<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.desal.2023.116431" target="_blank">https://dx.doi.org/10.1016/j.desal.2023.116431</a></p>2023-04-01T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.desal.2023.116431https://figshare.com/articles/journal_contribution/In-situ_desalination-coupled_electrolysis_with_concurrent_one-step-synthesis_of_value-added_chemicals/25036427CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/250364272023-04-01T00:00:00Z |
| spellingShingle | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals Byeong-ju Kim (7320773) Chemical sciences Physical chemistry Engineering Chemical engineering Materials engineering Desalination Bipolar membrane Electrocatalysis Seawater electrolysis Acid and base |
| status_str | publishedVersion |
| title | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals |
| title_full | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals |
| title_fullStr | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals |
| title_full_unstemmed | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals |
| title_short | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals |
| title_sort | In-situ desalination-coupled electrolysis with concurrent one-step-synthesis of value-added chemicals |
| topic | Chemical sciences Physical chemistry Engineering Chemical engineering Materials engineering Desalination Bipolar membrane Electrocatalysis Seawater electrolysis Acid and base |