Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential

<p dir="ltr">In this work, we study the electrochemical performance of Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> MXenes in the aqueous media and their application as a sensing platform for sma...

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محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: P. Abdul Rasheed (4863283) (author)
مؤلفون آخرون: Ravi P. Pandey (1449436) (author), Tricia Gomez (9624535) (author), Khadeeja A. Jabbar (16931796) (author), Kaitlyn Prenger (8587548) (author), Michael Naguib (1441495) (author), Brahim Aïssa (14157243) (author), Khaled A. Mahmoud (572646) (author)
منشور في: 2020
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author P. Abdul Rasheed (4863283)
author2 Ravi P. Pandey (1449436)
Tricia Gomez (9624535)
Khadeeja A. Jabbar (16931796)
Kaitlyn Prenger (8587548)
Michael Naguib (1441495)
Brahim Aïssa (14157243)
Khaled A. Mahmoud (572646)
author2_role author
author
author
author
author
author
author
author_facet P. Abdul Rasheed (4863283)
Ravi P. Pandey (1449436)
Tricia Gomez (9624535)
Khadeeja A. Jabbar (16931796)
Kaitlyn Prenger (8587548)
Michael Naguib (1441495)
Brahim Aïssa (14157243)
Khaled A. Mahmoud (572646)
author_role author
dc.creator.none.fl_str_mv P. Abdul Rasheed (4863283)
Ravi P. Pandey (1449436)
Tricia Gomez (9624535)
Khadeeja A. Jabbar (16931796)
Kaitlyn Prenger (8587548)
Michael Naguib (1441495)
Brahim Aïssa (14157243)
Khaled A. Mahmoud (572646)
dc.date.none.fl_str_mv 2020-10-01T00:00:00Z
dc.identifier.none.fl_str_mv 10.1016/j.elecom.2020.106811
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Nb-based_MXenes_for_efficient_electrochemical_sensing_of_small_biomolecules_in_the_anodic_potential/24270379
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Chemical sciences
Physical chemistry
Niobium
MXene
Electrochemical stability
Oxygen reduction reaction
Sensors
Small biomolecule detection
dc.title.none.fl_str_mv Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p dir="ltr">In this work, we study the electrochemical performance of Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> MXenes in the aqueous media and their application as a sensing platform for small biomolecules. Both Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> are electrochemically stable up to an anodic potential of 0.5 V. It was found that Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> is more electrochemically active than Nb<sub>2</sub>CT<sub>x</sub>. Based on this, Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> was evaluated for the electrochemical detection of aqueous media solutions containing ascorbic acid, uric acid and dopamine. This work opens the door for the wider application of Nb-based MXenes in aqueous electrochemical sensing applications.</p><h2>Other Information</h2><p dir="ltr">Published in: Electrochemistry Communications<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.elecom.2020.106811" target="_blank">https://dx.doi.org/10.1016/j.elecom.2020.106811</a></p>
eu_rights_str_mv openAccess
id Manara2_2b5866bb5b2f820cacdbedf7806fc0e3
identifier_str_mv 10.1016/j.elecom.2020.106811
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/24270379
publishDate 2020
repository.mail.fl_str_mv
repository.name.fl_str_mv
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rights_invalid_str_mv CC BY 4.0
spelling Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potentialP. Abdul Rasheed (4863283)Ravi P. Pandey (1449436)Tricia Gomez (9624535)Khadeeja A. Jabbar (16931796)Kaitlyn Prenger (8587548)Michael Naguib (1441495)Brahim Aïssa (14157243)Khaled A. Mahmoud (572646)Chemical sciencesPhysical chemistryNiobiumMXeneElectrochemical stabilityOxygen reduction reactionSensorsSmall biomolecule detection<p dir="ltr">In this work, we study the electrochemical performance of Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> MXenes in the aqueous media and their application as a sensing platform for small biomolecules. Both Nb<sub>2</sub>CT<sub>x</sub> and Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> are electrochemically stable up to an anodic potential of 0.5 V. It was found that Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> is more electrochemically active than Nb<sub>2</sub>CT<sub>x</sub>. Based on this, Nb<sub>4</sub>C<sub>3</sub>T<sub>x</sub> was evaluated for the electrochemical detection of aqueous media solutions containing ascorbic acid, uric acid and dopamine. This work opens the door for the wider application of Nb-based MXenes in aqueous electrochemical sensing applications.</p><h2>Other Information</h2><p dir="ltr">Published in: Electrochemistry Communications<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.elecom.2020.106811" target="_blank">https://dx.doi.org/10.1016/j.elecom.2020.106811</a></p>2020-10-01T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.elecom.2020.106811https://figshare.com/articles/journal_contribution/Nb-based_MXenes_for_efficient_electrochemical_sensing_of_small_biomolecules_in_the_anodic_potential/24270379CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/242703792020-10-01T00:00:00Z
spellingShingle Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
P. Abdul Rasheed (4863283)
Chemical sciences
Physical chemistry
Niobium
MXene
Electrochemical stability
Oxygen reduction reaction
Sensors
Small biomolecule detection
status_str publishedVersion
title Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
title_full Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
title_fullStr Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
title_full_unstemmed Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
title_short Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
title_sort Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential
topic Chemical sciences
Physical chemistry
Niobium
MXene
Electrochemical stability
Oxygen reduction reaction
Sensors
Small biomolecule detection