The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation
<p>Carbon dioxide (CO2) emissions have been the root cause for anthropogenic climate change. Decarbonisation strategies, particularly carbon capture and storage (CCS) are crucial for mitigating the risk of global warming. Among all current CO2 separation technologies, membrane separation has t...
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| مؤلفون آخرون: | , , , |
| منشور في: |
2022
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إضافة وسم
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| _version_ | 1864513567595692032 |
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| author | Fadel Abdul Hadi Juber (14151300) |
| author2 | Zeinab Abbas Jawad (13761609) Bridgid Lai Fui Chin (14151303) Swee Pin Yeap (1735042) Thiam Leng Chew (14151306) |
| author2_role | author author author author |
| author_facet | Fadel Abdul Hadi Juber (14151300) Zeinab Abbas Jawad (13761609) Bridgid Lai Fui Chin (14151303) Swee Pin Yeap (1735042) Thiam Leng Chew (14151306) |
| author_role | author |
| dc.creator.none.fl_str_mv | Fadel Abdul Hadi Juber (14151300) Zeinab Abbas Jawad (13761609) Bridgid Lai Fui Chin (14151303) Swee Pin Yeap (1735042) Thiam Leng Chew (14151306) |
| dc.date.none.fl_str_mv | 2022-11-22T21:13:45Z |
| dc.identifier.none.fl_str_mv | 10.1007/s10965-021-02500-6 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/The_prospect_of_synthesis_of_PES_PEG_blend_membranes_using_blend_NMP_DMF_for_CO2_N2_separation/21597369 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Macromolecular and materials chemistry Organic chemistry Materials Chemistry Organic Chemistry Polymers and Plastics |
| dc.title.none.fl_str_mv | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p>Carbon dioxide (CO2) emissions have been the root cause for anthropogenic climate change. Decarbonisation strategies, particularly carbon capture and storage (CCS) are crucial for mitigating the risk of global warming. Among all current CO2 separation technologies, membrane separation has the biggest potential for CCS as it is inexpensive, highly efficient, and simple to operate. Polymeric membranes are the preferred choice for the gas separation industry due to simpler methods of fabrication and lower costs compared to inorganic or mixed matrix membranes (MMMs). However, plasticisation and upper-bound trade-off between selectivity and permeability has limited the gas separation performance of polymeric membranes. Recently, researchers have found that the blending of glassy and rubbery polymers can effectively minimise trade-off between selectivity and permeability. Glassy poly(ethersulfone) (PES) and rubbery poly(ethylene) glycol (PEG) are polymers that are known to have a high affinity towards CO2. In this paper, PEG and PES are reviewed as potential polymer blend that can yield a final membrane with high CO2 permeance and CO2/nitrogen (N2) selectivity. Gas separation properties can be enhanced by using different solvents in the phase-inversion process. N-Methyl-2-Pyrrolidone (NMP) and Dimethylformamide (DMF) are common industrial solvents used for membrane fabrication. Both NMP and DMF are reviewed as prospective solvent blend that can improve the morphology and separation properties of PES/PEG blend membranes due to their effects on the membrane structure which increases permeation as well as selectivity. Thus, a PES/PEG blend polymeric membrane fabricated using NMP and DMF solvents is believed to be a major prospect for CO2/N2 gas separation.</p><h2>Other Information</h2> <p> Published in: Journal of Polymer Research<br> License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1007/s10965-021-02500-6" target="_blank">http://dx.doi.org/10.1007/s10965-021-02500-6</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_6f7027c1a80e140ed1b2f475a52762f7 |
| identifier_str_mv | 10.1007/s10965-021-02500-6 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/21597369 |
| publishDate | 2022 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separationFadel Abdul Hadi Juber (14151300)Zeinab Abbas Jawad (13761609)Bridgid Lai Fui Chin (14151303)Swee Pin Yeap (1735042)Thiam Leng Chew (14151306)Macromolecular and materials chemistryOrganic chemistryMaterials ChemistryOrganic ChemistryPolymers and Plastics<p>Carbon dioxide (CO2) emissions have been the root cause for anthropogenic climate change. Decarbonisation strategies, particularly carbon capture and storage (CCS) are crucial for mitigating the risk of global warming. Among all current CO2 separation technologies, membrane separation has the biggest potential for CCS as it is inexpensive, highly efficient, and simple to operate. Polymeric membranes are the preferred choice for the gas separation industry due to simpler methods of fabrication and lower costs compared to inorganic or mixed matrix membranes (MMMs). However, plasticisation and upper-bound trade-off between selectivity and permeability has limited the gas separation performance of polymeric membranes. Recently, researchers have found that the blending of glassy and rubbery polymers can effectively minimise trade-off between selectivity and permeability. Glassy poly(ethersulfone) (PES) and rubbery poly(ethylene) glycol (PEG) are polymers that are known to have a high affinity towards CO2. In this paper, PEG and PES are reviewed as potential polymer blend that can yield a final membrane with high CO2 permeance and CO2/nitrogen (N2) selectivity. Gas separation properties can be enhanced by using different solvents in the phase-inversion process. N-Methyl-2-Pyrrolidone (NMP) and Dimethylformamide (DMF) are common industrial solvents used for membrane fabrication. Both NMP and DMF are reviewed as prospective solvent blend that can improve the morphology and separation properties of PES/PEG blend membranes due to their effects on the membrane structure which increases permeation as well as selectivity. Thus, a PES/PEG blend polymeric membrane fabricated using NMP and DMF solvents is believed to be a major prospect for CO2/N2 gas separation.</p><h2>Other Information</h2> <p> Published in: Journal of Polymer Research<br> License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1007/s10965-021-02500-6" target="_blank">http://dx.doi.org/10.1007/s10965-021-02500-6</a></p>2022-11-22T21:13:45ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1007/s10965-021-02500-6https://figshare.com/articles/journal_contribution/The_prospect_of_synthesis_of_PES_PEG_blend_membranes_using_blend_NMP_DMF_for_CO2_N2_separation/21597369CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/215973692022-11-22T21:13:45Z |
| spellingShingle | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation Fadel Abdul Hadi Juber (14151300) Macromolecular and materials chemistry Organic chemistry Materials Chemistry Organic Chemistry Polymers and Plastics |
| status_str | publishedVersion |
| title | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation |
| title_full | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation |
| title_fullStr | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation |
| title_full_unstemmed | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation |
| title_short | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation |
| title_sort | The prospect of synthesis of PES/PEG blend membranes using blend NMP/DMF for CO2/N2 separation |
| topic | Macromolecular and materials chemistry Organic chemistry Materials Chemistry Organic Chemistry Polymers and Plastics |