Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts
<p dir="ltr">The extenuation of CO<sub>2</sub> emissions using electrochemical CO<sub>2</sub> reduction (ECR) is a promising approach. Electrochemical routes offer a number of benefits, including customizable layout, precise product modification, mild operatio...
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| مؤلفون آخرون: | , , |
| منشور في: |
2025
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| _version_ | 1864513551185477632 |
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| author | V.S.K. Yadav (20837744) |
| author2 | Mohammed A.H.S. Saad (20837747) Mohammed J. Al-Marri (1400581) Anand Kumar (24122) |
| author2_role | author author author |
| author_facet | V.S.K. Yadav (20837744) Mohammed A.H.S. Saad (20837747) Mohammed J. Al-Marri (1400581) Anand Kumar (24122) |
| author_role | author |
| dc.creator.none.fl_str_mv | V.S.K. Yadav (20837744) Mohammed A.H.S. Saad (20837747) Mohammed J. Al-Marri (1400581) Anand Kumar (24122) |
| dc.date.none.fl_str_mv | 2025-02-26T09:00:00Z |
| dc.identifier.none.fl_str_mv | 10.1016/j.ijhydene.2025.02.315 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/Quartz_crystal_microbalance_QCM_study_of_electrochemical_CO_sub_2_sub_reduction_on_Sn_electrocatalysts/28546559 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Engineering Environmental engineering Materials engineering Nanotechnology Quartz crystal microbalance (QCM) CO2 reduction Sn Frequency Mass |
| dc.title.none.fl_str_mv | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p dir="ltr">The extenuation of CO<sub>2</sub> emissions using electrochemical CO<sub>2</sub> reduction (ECR) is a promising approach. Electrochemical routes offer a number of benefits, including customizable layout, precise product modification, mild operational temperatures, and the ability to combine CO<sub>2</sub> reduction with the production of renewable electricity. Nevertheless, the essential technique for reprocessing CO<sub>2</sub> as a renewable resource is electrochemical CO<sub>2</sub> reduction, yet CO<sub>2</sub> adsorption/reduction on catalyst surfaces is challenging. To address these concerns, Mn<sub>3</sub>O<sub>4</sub> and Sn were produced in this work at room temperature via an electrodeposition technique, which was combined with a quartz crystal microbalance (QCM) sensor suitable for room-temperature monitoring of ECR. QCM is a compelling technique for closely inspecting the responses of CO<sub>2</sub> reduction in real time under various applied conditions. QCM was used for the first time to study the effects of Sn electrocatalysts for ECR research, and revealed the CO<sub>2</sub> adsorption/reduction capabilities of diverse Sn catalysts. A broad investigation showed the CO<sub>2</sub> reduction detecting ability of Sn coated QCM sensors at room temperature. The final results revealed that Sn catalysts' capacity to reduce CO<sub>2</sub> was evident both with and without CO<sub>2</sub> present in the solution of sodium bicarbonate electrolyte. For all the appropriate conditions, the effect of CO<sub>2</sub> saturated electrolyte solution on the frequency and mass change with time along with applied potential were discussed in detail.</p><h2>Other Information</h2><p dir="ltr">Published in: International Journal of Hydrogen Energy<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.ijhydene.2025.02.315" target="_blank">https://dx.doi.org/10.1016/j.ijhydene.2025.02.315</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_7cf294c8ef7436af9dff2974369d4b52 |
| identifier_str_mv | 10.1016/j.ijhydene.2025.02.315 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/28546559 |
| publishDate | 2025 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalystsV.S.K. Yadav (20837744)Mohammed A.H.S. Saad (20837747)Mohammed J. Al-Marri (1400581)Anand Kumar (24122)EngineeringEnvironmental engineeringMaterials engineeringNanotechnologyQuartz crystal microbalance (QCM)CO2 reductionSnFrequencyMass<p dir="ltr">The extenuation of CO<sub>2</sub> emissions using electrochemical CO<sub>2</sub> reduction (ECR) is a promising approach. Electrochemical routes offer a number of benefits, including customizable layout, precise product modification, mild operational temperatures, and the ability to combine CO<sub>2</sub> reduction with the production of renewable electricity. Nevertheless, the essential technique for reprocessing CO<sub>2</sub> as a renewable resource is electrochemical CO<sub>2</sub> reduction, yet CO<sub>2</sub> adsorption/reduction on catalyst surfaces is challenging. To address these concerns, Mn<sub>3</sub>O<sub>4</sub> and Sn were produced in this work at room temperature via an electrodeposition technique, which was combined with a quartz crystal microbalance (QCM) sensor suitable for room-temperature monitoring of ECR. QCM is a compelling technique for closely inspecting the responses of CO<sub>2</sub> reduction in real time under various applied conditions. QCM was used for the first time to study the effects of Sn electrocatalysts for ECR research, and revealed the CO<sub>2</sub> adsorption/reduction capabilities of diverse Sn catalysts. A broad investigation showed the CO<sub>2</sub> reduction detecting ability of Sn coated QCM sensors at room temperature. The final results revealed that Sn catalysts' capacity to reduce CO<sub>2</sub> was evident both with and without CO<sub>2</sub> present in the solution of sodium bicarbonate electrolyte. For all the appropriate conditions, the effect of CO<sub>2</sub> saturated electrolyte solution on the frequency and mass change with time along with applied potential were discussed in detail.</p><h2>Other Information</h2><p dir="ltr">Published in: International Journal of Hydrogen Energy<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.ijhydene.2025.02.315" target="_blank">https://dx.doi.org/10.1016/j.ijhydene.2025.02.315</a></p>2025-02-26T09:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.ijhydene.2025.02.315https://figshare.com/articles/journal_contribution/Quartz_crystal_microbalance_QCM_study_of_electrochemical_CO_sub_2_sub_reduction_on_Sn_electrocatalysts/28546559CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/285465592025-02-26T09:00:00Z |
| spellingShingle | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts V.S.K. Yadav (20837744) Engineering Environmental engineering Materials engineering Nanotechnology Quartz crystal microbalance (QCM) CO2 reduction Sn Frequency Mass |
| status_str | publishedVersion |
| title | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts |
| title_full | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts |
| title_fullStr | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts |
| title_full_unstemmed | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts |
| title_short | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts |
| title_sort | Quartz crystal microbalance (QCM) study of electrochemical CO<sub>2 </sub>reduction on Sn electrocatalysts |
| topic | Engineering Environmental engineering Materials engineering Nanotechnology Quartz crystal microbalance (QCM) CO2 reduction Sn Frequency Mass |