Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide

<p>In this study, an integrated system is proposed to form dolomite chemically from seawater and carbon dioxide. The system contains three main chemical processes: formation of magnesium hydroxide and calcium hydroxide, the reaction of magnesium hydroxide and calcium hydroxide with carbon diox...

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Main Author: Mohammed Al-Breiki (14152476) (author)
Other Authors: Yusuf Bicer (14158977) (author)
Published: 2019
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author Mohammed Al-Breiki (14152476)
author2 Yusuf Bicer (14158977)
author2_role author
author_facet Mohammed Al-Breiki (14152476)
Yusuf Bicer (14158977)
author_role author
dc.creator.none.fl_str_mv Mohammed Al-Breiki (14152476)
Yusuf Bicer (14158977)
dc.date.none.fl_str_mv 2019-09-24T00:00:00Z
dc.identifier.none.fl_str_mv 10.1007/s42452-019-1313-7
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Thermodynamic_analysis_of_theoretical_dolomite_formation_from_seawater_and_captured_carbon_dioxide/21597987
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Earth sciences
Geology
Carbon capture
Dolomite
Energy
Exergy
Efficiency
Building material
dc.title.none.fl_str_mv Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p>In this study, an integrated system is proposed to form dolomite chemically from seawater and carbon dioxide. The system contains three main chemical processes: formation of magnesium hydroxide and calcium hydroxide, the reaction of magnesium hydroxide and calcium hydroxide with carbon dioxide, and the formation of dolomite. Based on the fundamental thermodynamic laws, energy and exergy analyses, and performance assessment of the proposed system is carried out. Furthermore, the effects of varying temperatures of each process on various energy and exergy efficiencies are assessed through parametric studies. The results show that formation of dolomite is favorable at temperature ranges of 313–470 K based on the thermodynamic study. The exergy efficiency of dolomite formation is found to be about 23.8% and the results reveal that the dolomite formation process has the specific exergy destruction value of 29.6 kJ/mol among other sub-processes. The results suggest that the proposed system may provide enhanced options for low-temperature dolomite formation using seawater and captured carbon dioxide once the reaction kinetics is favored.</p><h2>Other Information</h2> <p> Published in: SN Applied Sciences<br> License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1007/s42452-019-1313-7" target="_blank">http://dx.doi.org/10.1007/s42452-019-1313-7</a></p>
eu_rights_str_mv openAccess
id Manara2_8fb6d602e3d77f3ed92b92a1f34eb040
identifier_str_mv 10.1007/s42452-019-1313-7
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/21597987
publishDate 2019
repository.mail.fl_str_mv
repository.name.fl_str_mv
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rights_invalid_str_mv CC BY 4.0
spelling Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxideMohammed Al-Breiki (14152476)Yusuf Bicer (14158977)Earth sciencesGeologyCarbon captureDolomiteEnergyExergyEfficiencyBuilding material<p>In this study, an integrated system is proposed to form dolomite chemically from seawater and carbon dioxide. The system contains three main chemical processes: formation of magnesium hydroxide and calcium hydroxide, the reaction of magnesium hydroxide and calcium hydroxide with carbon dioxide, and the formation of dolomite. Based on the fundamental thermodynamic laws, energy and exergy analyses, and performance assessment of the proposed system is carried out. Furthermore, the effects of varying temperatures of each process on various energy and exergy efficiencies are assessed through parametric studies. The results show that formation of dolomite is favorable at temperature ranges of 313–470 K based on the thermodynamic study. The exergy efficiency of dolomite formation is found to be about 23.8% and the results reveal that the dolomite formation process has the specific exergy destruction value of 29.6 kJ/mol among other sub-processes. The results suggest that the proposed system may provide enhanced options for low-temperature dolomite formation using seawater and captured carbon dioxide once the reaction kinetics is favored.</p><h2>Other Information</h2> <p> Published in: SN Applied Sciences<br> License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1007/s42452-019-1313-7" target="_blank">http://dx.doi.org/10.1007/s42452-019-1313-7</a></p>2019-09-24T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1007/s42452-019-1313-7https://figshare.com/articles/journal_contribution/Thermodynamic_analysis_of_theoretical_dolomite_formation_from_seawater_and_captured_carbon_dioxide/21597987CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/215979872019-09-24T00:00:00Z
spellingShingle Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
Mohammed Al-Breiki (14152476)
Earth sciences
Geology
Carbon capture
Dolomite
Energy
Exergy
Efficiency
Building material
status_str publishedVersion
title Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
title_full Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
title_fullStr Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
title_full_unstemmed Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
title_short Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
title_sort Thermodynamic analysis of theoretical dolomite formation from seawater and captured carbon dioxide
topic Earth sciences
Geology
Carbon capture
Dolomite
Energy
Exergy
Efficiency
Building material