Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design
<p dir="ltr">Titan yellow (TY), a triazene azo dye, was removed from contaminated wastewater samples using a green adsorbent recycled from Aloe vera leaves (AV) waste. Two adsorbents were developed—air-dried Aloe vera (ADAV) and thermally treated Aloe vera (TTAV). Adsorption efficacy...
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| مؤلفون آخرون: | , , |
| منشور في: |
2019
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| _version_ | 1864513525416722432 |
|---|---|
| author | Marwa El-Azazy (14152794) |
| author2 | Sarra Dimassi (18095365) Ahmed El-Shafie (6786179) Ahmed Issa (4800633) |
| author2_role | author author author |
| author_facet | Marwa El-Azazy (14152794) Sarra Dimassi (18095365) Ahmed El-Shafie (6786179) Ahmed Issa (4800633) |
| author_role | author |
| dc.creator.none.fl_str_mv | Marwa El-Azazy (14152794) Sarra Dimassi (18095365) Ahmed El-Shafie (6786179) Ahmed Issa (4800633) |
| dc.date.none.fl_str_mv | 2019-11-13T03:00:00Z |
| dc.identifier.none.fl_str_mv | 10.3390/app9224856 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/Bio-Waste_Aloe_vera_Leaves_as_an_Efficient_Adsorbent_for_Titan_Yellow_from_Wastewater_Structuring_of_a_Novel_Adsorbent_Using_Plackett-Burman_Factorial_Design/25334524 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Chemical sciences Analytical chemistry Engineering Materials engineering Aloe vera (AV) leaves Plackett–Burman Design (PBD) Titan yellow (TY) %removal and adsorption capacity (qe) characterization equilibrium kinetics |
| dc.title.none.fl_str_mv | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p dir="ltr">Titan yellow (TY), a triazene azo dye, was removed from contaminated wastewater samples using a green adsorbent recycled from Aloe vera leaves (AV) waste. Two adsorbents were developed—air-dried Aloe vera (ADAV) and thermally treated Aloe vera (TTAV). Adsorption efficacy of both adsorbents was assessed in terms of percent removal (%R) of TY and adsorption capacity (qe). ADAV had a better performance compared to TTAV. Plackett–Burman design (PBD) was exploited to establish the experimental pattern of the study. Four variables were studied: pH, adsorbent dose (AD), dye concentration (DC), and stirring time (ST). Analysis of variance (ANOVA) at 95.0 confidence interval (CI), control, and quality charts helped establish regression model(s). Characterization of both adsorbents was performed using FT-IR/Raman spectroscopy together with TGA/dTGA and SEM/energy dispersive X-ray spectroscopy (EDX) analyses. Textural properties were determined using nitrogen adsorption isotherms at 77 K. Results showed that the surface areas of ADAV and TTAV300 were 3.940 and 7.076 m2/g, respectively. Raman analysis showed that the TTAV had clear D- and G-bands. Equilibrium studies revealed that data were well fitted to Freundlich isotherm with a maximum adsorption capacity of 55.25 mg/g using Langmuir equation, and the adsorption was physisorption. Adsorption followed a pseudo-second order that occurred in two steps—diffusion and then adsorption.</p><h2>Other Information</h2><p dir="ltr">Published in: Applied Sciences<br>License: <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank">https://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.3390/app9224856" target="_blank">https://dx.doi.org/10.3390/app9224856</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_9a432405df24b802c2d089a968298cd8 |
| identifier_str_mv | 10.3390/app9224856 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/25334524 |
| publishDate | 2019 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial DesignMarwa El-Azazy (14152794)Sarra Dimassi (18095365)Ahmed El-Shafie (6786179)Ahmed Issa (4800633)Chemical sciencesAnalytical chemistryEngineeringMaterials engineeringAloe vera (AV) leavesPlackett–Burman Design (PBD)Titan yellow (TY)%removal and adsorption capacity (qe)characterizationequilibriumkinetics<p dir="ltr">Titan yellow (TY), a triazene azo dye, was removed from contaminated wastewater samples using a green adsorbent recycled from Aloe vera leaves (AV) waste. Two adsorbents were developed—air-dried Aloe vera (ADAV) and thermally treated Aloe vera (TTAV). Adsorption efficacy of both adsorbents was assessed in terms of percent removal (%R) of TY and adsorption capacity (qe). ADAV had a better performance compared to TTAV. Plackett–Burman design (PBD) was exploited to establish the experimental pattern of the study. Four variables were studied: pH, adsorbent dose (AD), dye concentration (DC), and stirring time (ST). Analysis of variance (ANOVA) at 95.0 confidence interval (CI), control, and quality charts helped establish regression model(s). Characterization of both adsorbents was performed using FT-IR/Raman spectroscopy together with TGA/dTGA and SEM/energy dispersive X-ray spectroscopy (EDX) analyses. Textural properties were determined using nitrogen adsorption isotherms at 77 K. Results showed that the surface areas of ADAV and TTAV300 were 3.940 and 7.076 m2/g, respectively. Raman analysis showed that the TTAV had clear D- and G-bands. Equilibrium studies revealed that data were well fitted to Freundlich isotherm with a maximum adsorption capacity of 55.25 mg/g using Langmuir equation, and the adsorption was physisorption. Adsorption followed a pseudo-second order that occurred in two steps—diffusion and then adsorption.</p><h2>Other Information</h2><p dir="ltr">Published in: Applied Sciences<br>License: <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank">https://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.3390/app9224856" target="_blank">https://dx.doi.org/10.3390/app9224856</a></p>2019-11-13T03:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.3390/app9224856https://figshare.com/articles/journal_contribution/Bio-Waste_Aloe_vera_Leaves_as_an_Efficient_Adsorbent_for_Titan_Yellow_from_Wastewater_Structuring_of_a_Novel_Adsorbent_Using_Plackett-Burman_Factorial_Design/25334524CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/253345242019-11-13T03:00:00Z |
| spellingShingle | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design Marwa El-Azazy (14152794) Chemical sciences Analytical chemistry Engineering Materials engineering Aloe vera (AV) leaves Plackett–Burman Design (PBD) Titan yellow (TY) %removal and adsorption capacity (qe) characterization equilibrium kinetics |
| status_str | publishedVersion |
| title | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design |
| title_full | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design |
| title_fullStr | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design |
| title_full_unstemmed | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design |
| title_short | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design |
| title_sort | Bio-Waste Aloe vera Leaves as an Efficient Adsorbent for Titan Yellow from Wastewater: Structuring of a Novel Adsorbent Using Plackett-Burman Factorial Design |
| topic | Chemical sciences Analytical chemistry Engineering Materials engineering Aloe vera (AV) leaves Plackett–Burman Design (PBD) Titan yellow (TY) %removal and adsorption capacity (qe) characterization equilibrium kinetics |