Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance

<p dir="ltr">This study demonstrates a novel method for enhancing ultrafiltration membrane performance by integrating Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene nanomaterials into a polyethersulfone (PES) matrix, creating mixed matrix membranes...

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Main Author: Ahmed Nabeeh (11084772) (author)
Other Authors: Omnya Abdalla (17100211) (author), Abdul Rehman (604331) (author), Zafar Khan Ghouri (1407580) (author), Ahmed Abdel-Wahab (1748986) (author), Khaled Mahmoud (699380) (author), Ahmed Abdala (5743205) (author)
Published: 2024
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author Ahmed Nabeeh (11084772)
author2 Omnya Abdalla (17100211)
Abdul Rehman (604331)
Zafar Khan Ghouri (1407580)
Ahmed Abdel-Wahab (1748986)
Khaled Mahmoud (699380)
Ahmed Abdala (5743205)
author2_role author
author
author
author
author
author
author_facet Ahmed Nabeeh (11084772)
Omnya Abdalla (17100211)
Abdul Rehman (604331)
Zafar Khan Ghouri (1407580)
Ahmed Abdel-Wahab (1748986)
Khaled Mahmoud (699380)
Ahmed Abdala (5743205)
author_role author
dc.creator.none.fl_str_mv Ahmed Nabeeh (11084772)
Omnya Abdalla (17100211)
Abdul Rehman (604331)
Zafar Khan Ghouri (1407580)
Ahmed Abdel-Wahab (1748986)
Khaled Mahmoud (699380)
Ahmed Abdala (5743205)
dc.date.none.fl_str_mv 2024-10-30T03:00:00Z
dc.identifier.none.fl_str_mv 10.1016/j.seppur.2024.127285
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Ultrafiltration_polyethersulfone-MXene_mixed_matrix_membranes_with_enhanced_air_dehumidification_and_oil-water_separation_performance/25827127
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Engineering
Materials engineering
Polyethersulfone
Mixed matrix membranes
Ultrafiltration
Air-dehumidification, MXene
Oil–water separation
dc.title.none.fl_str_mv Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p dir="ltr">This study demonstrates a novel method for enhancing ultrafiltration membrane performance by integrating Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene nanomaterials into a polyethersulfone (PES) matrix, creating mixed matrix membranes (MMMs). The structure and surface characteristics of the fabricated MMM containing different loadings of Mxene were thoroughly characterized using SEM, TEM, XRD, and AFM. The membrane performance in water–oil separation and as support for air-dehumidification membranes were investigated. Incorporating Mxene improved the membrane morphology, hydrophilicity, and mechanical properties. Moreover, the PES-MXene MMMs exhibited ultra-high water flux of 2280 LMH/bar, 98 % oil rejection, and a water vapor permeance (WVP) of 18,100 GPU, significantly outperforming the control PES membranes. Long-term stability assessments for 16 h revealed the optimum MMM containing 0.1 wt MXene has an emulsion flux of 180 % of the control PES membrane. Antifouling testing using 1000 mg/L milk solution also demonstrated that the MMM has a 50 % reduction in irreversible fouling than the control PES membrane. These results establish the PES-MXene MMMs as a high-performance solution for water treatment and air-dehumidification applications, opening new application avenues.</p><h2>Other Information</h2><p dir="ltr">Published in: Separation and Purification Technology<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.seppur.2024.127285" target="_blank">https://dx.doi.org/10.1016/j.seppur.2024.127285</a></p>
eu_rights_str_mv openAccess
id Manara2_9f86df8b4839d69dcecae038bf3d7fce
identifier_str_mv 10.1016/j.seppur.2024.127285
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/25827127
publishDate 2024
repository.mail.fl_str_mv
repository.name.fl_str_mv
repository_id_str
rights_invalid_str_mv CC BY 4.0
spelling Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performanceAhmed Nabeeh (11084772)Omnya Abdalla (17100211)Abdul Rehman (604331)Zafar Khan Ghouri (1407580)Ahmed Abdel-Wahab (1748986)Khaled Mahmoud (699380)Ahmed Abdala (5743205)EngineeringMaterials engineeringPolyethersulfoneMixed matrix membranesUltrafiltrationAir-dehumidification, MXeneOil–water separation<p dir="ltr">This study demonstrates a novel method for enhancing ultrafiltration membrane performance by integrating Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene nanomaterials into a polyethersulfone (PES) matrix, creating mixed matrix membranes (MMMs). The structure and surface characteristics of the fabricated MMM containing different loadings of Mxene were thoroughly characterized using SEM, TEM, XRD, and AFM. The membrane performance in water–oil separation and as support for air-dehumidification membranes were investigated. Incorporating Mxene improved the membrane morphology, hydrophilicity, and mechanical properties. Moreover, the PES-MXene MMMs exhibited ultra-high water flux of 2280 LMH/bar, 98 % oil rejection, and a water vapor permeance (WVP) of 18,100 GPU, significantly outperforming the control PES membranes. Long-term stability assessments for 16 h revealed the optimum MMM containing 0.1 wt MXene has an emulsion flux of 180 % of the control PES membrane. Antifouling testing using 1000 mg/L milk solution also demonstrated that the MMM has a 50 % reduction in irreversible fouling than the control PES membrane. These results establish the PES-MXene MMMs as a high-performance solution for water treatment and air-dehumidification applications, opening new application avenues.</p><h2>Other Information</h2><p dir="ltr">Published in: Separation and Purification Technology<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.seppur.2024.127285" target="_blank">https://dx.doi.org/10.1016/j.seppur.2024.127285</a></p>2024-10-30T03:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.seppur.2024.127285https://figshare.com/articles/journal_contribution/Ultrafiltration_polyethersulfone-MXene_mixed_matrix_membranes_with_enhanced_air_dehumidification_and_oil-water_separation_performance/25827127CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/258271272024-10-30T03:00:00Z
spellingShingle Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
Ahmed Nabeeh (11084772)
Engineering
Materials engineering
Polyethersulfone
Mixed matrix membranes
Ultrafiltration
Air-dehumidification, MXene
Oil–water separation
status_str publishedVersion
title Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
title_full Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
title_fullStr Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
title_full_unstemmed Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
title_short Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
title_sort Ultrafiltration polyethersulfone-MXene mixed matrix membranes with enhanced air dehumidification and oil-water separation performance
topic Engineering
Materials engineering
Polyethersulfone
Mixed matrix membranes
Ultrafiltration
Air-dehumidification, MXene
Oil–water separation