The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions

<p dir="ltr">Numerical models were developed to investigate the significance of ferrous ion oxidation in carbon steel corrosion in near-neutral aerated aqueous solutions. The results demonstrated that the inclusion of ferrous ion oxidation improved the accuracy of pH predictions in d...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Ke Wang (82395) (author)
مؤلفون آخرون: Hanan Farhat (14590031) (author), Mariano Iannuzzi (2178926) (author), Katerina Lepkova (19237264) (author)
منشور في: 2023
الموضوعات:
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author Ke Wang (82395)
author2 Hanan Farhat (14590031)
Mariano Iannuzzi (2178926)
Katerina Lepkova (19237264)
author2_role author
author
author
author_facet Ke Wang (82395)
Hanan Farhat (14590031)
Mariano Iannuzzi (2178926)
Katerina Lepkova (19237264)
author_role author
dc.creator.none.fl_str_mv Ke Wang (82395)
Hanan Farhat (14590031)
Mariano Iannuzzi (2178926)
Katerina Lepkova (19237264)
dc.date.none.fl_str_mv 2023-12-06T15:00:00Z
dc.identifier.none.fl_str_mv 10.1016/j.elecom.2023.107637
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/The_significance_of_ferrous_ion_oxidation_during_corrosion_of_carbon_steel_in_aerated_near-neutral_aqueous_solutions/26389414
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Chemical sciences
Physical chemistry
Engineering
Resources engineering and extractive metallurgy
Modelling
Ferrous ion oxidation
pH
Crevice
Carbon steel
dc.title.none.fl_str_mv The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p dir="ltr">Numerical models were developed to investigate the significance of ferrous ion oxidation in carbon steel corrosion in near-neutral aerated aqueous solutions. The results demonstrated that the inclusion of ferrous ion oxidation improved the accuracy of pH predictions in deep crevices under cathodic protection and Evan's drop exposure conditions, closely matching experimental observations. The reaction rate for ferrous ion oxidation was found to be between 1 × 10<sup>14</sup> and 2 × 10<sup>14</sup> (mol/L)<sup>-2</sup> atm<sup>−1</sup> min<sup>−1</sup>. These findings highlight the importance of considering ferrous ion oxidation when modelling carbon steel corrosion in near-neutral aerated aqueous solutions.</p><h2>Other Information</h2><p dir="ltr">Published in: Electrochemistry Communications<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.elecom.2023.107637" target="_blank">https://dx.doi.org/10.1016/j.elecom.2023.107637</a></p>
eu_rights_str_mv openAccess
id Manara2_b5afe81892b54c8fcd13ece84f450e42
identifier_str_mv 10.1016/j.elecom.2023.107637
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/26389414
publishDate 2023
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rights_invalid_str_mv CC BY 4.0
spelling The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutionsKe Wang (82395)Hanan Farhat (14590031)Mariano Iannuzzi (2178926)Katerina Lepkova (19237264)Chemical sciencesPhysical chemistryEngineeringResources engineering and extractive metallurgyModellingFerrous ion oxidationpHCreviceCarbon steel<p dir="ltr">Numerical models were developed to investigate the significance of ferrous ion oxidation in carbon steel corrosion in near-neutral aerated aqueous solutions. The results demonstrated that the inclusion of ferrous ion oxidation improved the accuracy of pH predictions in deep crevices under cathodic protection and Evan's drop exposure conditions, closely matching experimental observations. The reaction rate for ferrous ion oxidation was found to be between 1 × 10<sup>14</sup> and 2 × 10<sup>14</sup> (mol/L)<sup>-2</sup> atm<sup>−1</sup> min<sup>−1</sup>. These findings highlight the importance of considering ferrous ion oxidation when modelling carbon steel corrosion in near-neutral aerated aqueous solutions.</p><h2>Other Information</h2><p dir="ltr">Published in: Electrochemistry Communications<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.elecom.2023.107637" target="_blank">https://dx.doi.org/10.1016/j.elecom.2023.107637</a></p>2023-12-06T15:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.elecom.2023.107637https://figshare.com/articles/journal_contribution/The_significance_of_ferrous_ion_oxidation_during_corrosion_of_carbon_steel_in_aerated_near-neutral_aqueous_solutions/26389414CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/263894142023-12-06T15:00:00Z
spellingShingle The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
Ke Wang (82395)
Chemical sciences
Physical chemistry
Engineering
Resources engineering and extractive metallurgy
Modelling
Ferrous ion oxidation
pH
Crevice
Carbon steel
status_str publishedVersion
title The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
title_full The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
title_fullStr The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
title_full_unstemmed The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
title_short The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
title_sort The significance of ferrous ion oxidation during corrosion of carbon steel in aerated near-neutral aqueous solutions
topic Chemical sciences
Physical chemistry
Engineering
Resources engineering and extractive metallurgy
Modelling
Ferrous ion oxidation
pH
Crevice
Carbon steel