Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater

<p>This study investigates the development and application of bio-waste-derived adsorbents for the removal of boron from groundwater. The boron removal from groundwater was explored by bio-waste-derived adsorbents such as roasted date pits (RDPs) and modified roasted date pits (MDPs) by mercap...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Ayesha Y. Ahmad (14152779) (author)
مؤلفون آخرون: Mohammad A. Al-Ghouti (8882054) (author), Majeda Khraisheh (1349376) (author), Nabil Zouari (9193418) (author)
منشور في: 2022
الموضوعات:
الوسوم: إضافة وسم
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author Ayesha Y. Ahmad (14152779)
author2 Mohammad A. Al-Ghouti (8882054)
Majeda Khraisheh (1349376)
Nabil Zouari (9193418)
author2_role author
author
author
author_facet Ayesha Y. Ahmad (14152779)
Mohammad A. Al-Ghouti (8882054)
Majeda Khraisheh (1349376)
Nabil Zouari (9193418)
author_role author
dc.creator.none.fl_str_mv Ayesha Y. Ahmad (14152779)
Mohammad A. Al-Ghouti (8882054)
Majeda Khraisheh (1349376)
Nabil Zouari (9193418)
dc.date.none.fl_str_mv 2022-08-01T00:00:00Z
dc.identifier.none.fl_str_mv 10.1016/j.gsd.2022.100793
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Development_and_application_of_bio-waste-derived_adsorbents_for_the_removal_of_boron_from_groundwater/24745113
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Engineering
Chemical engineering
Environmental sciences
Ecological applications
Pollution and contamination
Groundwater
Treatment
Natural adsorbents
Bio-waste
Adsorption isotherms
Boron
dc.title.none.fl_str_mv Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p>This study investigates the development and application of bio-waste-derived adsorbents for the removal of boron from groundwater. The boron removal from groundwater was explored by bio-waste-derived adsorbents such as roasted date pits (RDPs) and modified roasted date pits (MDPs) by mercaptoacetic acid. The results were also compared with the commercially available adsorbents such as activated carbon and bentonite. Several experimental conditions, including pH, temperature, and initial concentration were investigated. Various analytical techniques were used to investigate surface characterizations, functional groups and morphological changes of the adsorbents via Fourier transform infrared spectroscopy (FTIR), Brunauer Emmett Teller (BET), and scanning electron microscopy (SEM). In addition, four adsorption models are utilized to analyze the adsorption process, including Langmuir, Dubinin-Radushkevich, Freundlich, and Temkin. The results showed that the modified roasted date pits (MDPs) could be used as an affordable, environmentally friendly, and effective adsorbent for boron removal from groundwater (GW). Negative Gibbs energy (ΔG°) values imply a spontaneous and favorable adsorption process, which is more favorable and spontaneous at high temperatures. The adsorption process was governed by positive entropy values (ΔS°), which suggests that the adsorbate–adsorbent complex may have undergone structural alterations or readjustments.</p><h2>Other Information</h2> <p> Published in: Groundwater for Sustainable Development<br> License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.gsd.2022.100793" target="_blank">https://dx.doi.org/10.1016/j.gsd.2022.100793</a></p>
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identifier_str_mv 10.1016/j.gsd.2022.100793
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/24745113
publishDate 2022
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rights_invalid_str_mv CC BY 4.0
spelling Development and application of bio-waste-derived adsorbents for the removal of boron from groundwaterAyesha Y. Ahmad (14152779)Mohammad A. Al-Ghouti (8882054)Majeda Khraisheh (1349376)Nabil Zouari (9193418)EngineeringChemical engineeringEnvironmental sciencesEcological applicationsPollution and contaminationGroundwaterTreatmentNatural adsorbentsBio-wasteAdsorption isothermsBoron<p>This study investigates the development and application of bio-waste-derived adsorbents for the removal of boron from groundwater. The boron removal from groundwater was explored by bio-waste-derived adsorbents such as roasted date pits (RDPs) and modified roasted date pits (MDPs) by mercaptoacetic acid. The results were also compared with the commercially available adsorbents such as activated carbon and bentonite. Several experimental conditions, including pH, temperature, and initial concentration were investigated. Various analytical techniques were used to investigate surface characterizations, functional groups and morphological changes of the adsorbents via Fourier transform infrared spectroscopy (FTIR), Brunauer Emmett Teller (BET), and scanning electron microscopy (SEM). In addition, four adsorption models are utilized to analyze the adsorption process, including Langmuir, Dubinin-Radushkevich, Freundlich, and Temkin. The results showed that the modified roasted date pits (MDPs) could be used as an affordable, environmentally friendly, and effective adsorbent for boron removal from groundwater (GW). Negative Gibbs energy (ΔG°) values imply a spontaneous and favorable adsorption process, which is more favorable and spontaneous at high temperatures. The adsorption process was governed by positive entropy values (ΔS°), which suggests that the adsorbate–adsorbent complex may have undergone structural alterations or readjustments.</p><h2>Other Information</h2> <p> Published in: Groundwater for Sustainable Development<br> License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.gsd.2022.100793" target="_blank">https://dx.doi.org/10.1016/j.gsd.2022.100793</a></p>2022-08-01T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.gsd.2022.100793https://figshare.com/articles/journal_contribution/Development_and_application_of_bio-waste-derived_adsorbents_for_the_removal_of_boron_from_groundwater/24745113CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/247451132022-08-01T00:00:00Z
spellingShingle Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
Ayesha Y. Ahmad (14152779)
Engineering
Chemical engineering
Environmental sciences
Ecological applications
Pollution and contamination
Groundwater
Treatment
Natural adsorbents
Bio-waste
Adsorption isotherms
Boron
status_str publishedVersion
title Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
title_full Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
title_fullStr Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
title_full_unstemmed Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
title_short Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
title_sort Development and application of bio-waste-derived adsorbents for the removal of boron from groundwater
topic Engineering
Chemical engineering
Environmental sciences
Ecological applications
Pollution and contamination
Groundwater
Treatment
Natural adsorbents
Bio-waste
Adsorption isotherms
Boron