Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar

<p dir="ltr">This study aims to investigate the groundwater (GW) quality in Qatar to be utilized in domestic and agricultural uses. The integrated physiochemical analysis along with hydrochemical faces analysis, geochemical modeling, statistical and geostatistical analysis was conduc...

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Main Author: Ayesha Y. Ahmad (14152779) (author)
Other Authors: Mohammad A. Al-Ghouti (8882054) (author), Majeda Khraisheh (1349376) (author), Nabil Zouari (9193418) (author)
Published: 2020
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_version_ 1864513557748514816
author Ayesha Y. Ahmad (14152779)
author2 Mohammad A. Al-Ghouti (8882054)
Majeda Khraisheh (1349376)
Nabil Zouari (9193418)
author2_role author
author
author
author_facet Ayesha Y. Ahmad (14152779)
Mohammad A. Al-Ghouti (8882054)
Majeda Khraisheh (1349376)
Nabil Zouari (9193418)
author_role author
dc.creator.none.fl_str_mv Ayesha Y. Ahmad (14152779)
Mohammad A. Al-Ghouti (8882054)
Majeda Khraisheh (1349376)
Nabil Zouari (9193418)
dc.date.none.fl_str_mv 2020-10-01T00:00:00Z
dc.identifier.none.fl_str_mv 10.1016/j.gsd.2020.100467
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Hydrogeochemical_characterization_and_quality_evaluation_of_groundwater_suitability_for_domestic_and_agricultural_uses_in_the_state_of_Qatar/24249835
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Engineering
Chemical engineering
Environmental sciences
Environmental biotechnology
Groundwater
Hydrogeochemical characterization
Domestic use
Agriculture use
Geochemical modeling
Geo-statistical analysis
dc.title.none.fl_str_mv Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p dir="ltr">This study aims to investigate the groundwater (GW) quality in Qatar to be utilized in domestic and agricultural uses. The integrated physiochemical analysis along with hydrochemical faces analysis, geochemical modeling, statistical and geostatistical analysis was conducted. The results showed that the GW samples mainly have the following cations Na<sup>+</sup> > Ca<sup>2+</sup> > Mg<sup>2+</sup> >K<sup>+</sup> abundantly, while Cl<sup>−</sup> > SO<sub>4</sub><sup>2−</sup> > HCO<sub>3</sub><sup>−</sup> > NO<sub>3</sub><sup>−</sup> were the main anions. The obtained analytical values of the GW samples were plotted on Piper, Schoeller, Ternary, Ludwig Langelier, Giggenbach Triangle, Durov, and stiff graphs. The hydrogeochemical facies and the obtained graphs confirmed that most of the analyzed GW samples fall into two types of water namely calcium-chloride-type (SO<sub>4</sub>–Cl and Ca–Mg) and sodium-chloride-type (SO<sub>4</sub>–Cl and Na–K). Three principal components were yielded from the principal component analysis (PCA), which are the first principal component (PC1), second principal component (PC2), and third principal component (PC3) with ≥1 Eigenvalues, and total variance of 49, 31, and 19.9%, respectively. A positive loading of Mg, Th, Sr, Ca, TDS, SO4, Li, Cl, F, Br, Cd, K, Ba, and Na has been shown by the PC1; representing the factors which are contributing to the high salinity of the GW due to the salt water intrusion and the mineralization of rocks and soil which is supported by the water type classification and saturation indices. The PC2 showed a negative loading of U, Al, Se, Mo, Mg, and temperature, which could be associated with a localized sedimentary depositional or hydrogeochemical environment. The PC3 showed a positive loading of Ni, Zn, Be, pH, Cu, Co, Fe, B, V, and TOC, which indicates the dissolution and precipitation (reducing and oxidizing factor) such as iron which is a redox-sensitive variable.</p><h2>Other Information</h2><p dir="ltr">Published in: Groundwater for Sustainable Development<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.gsd.2020.100467" target="_blank">https://dx.doi.org/10.1016/j.gsd.2020.100467</a></p>
eu_rights_str_mv openAccess
id Manara2_be27a1cd2c468bdc11391bace3010b7e
identifier_str_mv 10.1016/j.gsd.2020.100467
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/24249835
publishDate 2020
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rights_invalid_str_mv CC BY 4.0
spelling Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of QatarAyesha Y. Ahmad (14152779)Mohammad A. Al-Ghouti (8882054)Majeda Khraisheh (1349376)Nabil Zouari (9193418)EngineeringChemical engineeringEnvironmental sciencesEnvironmental biotechnologyGroundwaterHydrogeochemical characterizationDomestic useAgriculture useGeochemical modelingGeo-statistical analysis<p dir="ltr">This study aims to investigate the groundwater (GW) quality in Qatar to be utilized in domestic and agricultural uses. The integrated physiochemical analysis along with hydrochemical faces analysis, geochemical modeling, statistical and geostatistical analysis was conducted. The results showed that the GW samples mainly have the following cations Na<sup>+</sup> > Ca<sup>2+</sup> > Mg<sup>2+</sup> >K<sup>+</sup> abundantly, while Cl<sup>−</sup> > SO<sub>4</sub><sup>2−</sup> > HCO<sub>3</sub><sup>−</sup> > NO<sub>3</sub><sup>−</sup> were the main anions. The obtained analytical values of the GW samples were plotted on Piper, Schoeller, Ternary, Ludwig Langelier, Giggenbach Triangle, Durov, and stiff graphs. The hydrogeochemical facies and the obtained graphs confirmed that most of the analyzed GW samples fall into two types of water namely calcium-chloride-type (SO<sub>4</sub>–Cl and Ca–Mg) and sodium-chloride-type (SO<sub>4</sub>–Cl and Na–K). Three principal components were yielded from the principal component analysis (PCA), which are the first principal component (PC1), second principal component (PC2), and third principal component (PC3) with ≥1 Eigenvalues, and total variance of 49, 31, and 19.9%, respectively. A positive loading of Mg, Th, Sr, Ca, TDS, SO4, Li, Cl, F, Br, Cd, K, Ba, and Na has been shown by the PC1; representing the factors which are contributing to the high salinity of the GW due to the salt water intrusion and the mineralization of rocks and soil which is supported by the water type classification and saturation indices. The PC2 showed a negative loading of U, Al, Se, Mo, Mg, and temperature, which could be associated with a localized sedimentary depositional or hydrogeochemical environment. The PC3 showed a positive loading of Ni, Zn, Be, pH, Cu, Co, Fe, B, V, and TOC, which indicates the dissolution and precipitation (reducing and oxidizing factor) such as iron which is a redox-sensitive variable.</p><h2>Other Information</h2><p dir="ltr">Published in: Groundwater for Sustainable Development<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.gsd.2020.100467" target="_blank">https://dx.doi.org/10.1016/j.gsd.2020.100467</a></p>2020-10-01T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.gsd.2020.100467https://figshare.com/articles/journal_contribution/Hydrogeochemical_characterization_and_quality_evaluation_of_groundwater_suitability_for_domestic_and_agricultural_uses_in_the_state_of_Qatar/24249835CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/242498352020-10-01T00:00:00Z
spellingShingle Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
Ayesha Y. Ahmad (14152779)
Engineering
Chemical engineering
Environmental sciences
Environmental biotechnology
Groundwater
Hydrogeochemical characterization
Domestic use
Agriculture use
Geochemical modeling
Geo-statistical analysis
status_str publishedVersion
title Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
title_full Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
title_fullStr Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
title_full_unstemmed Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
title_short Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
title_sort Hydrogeochemical characterization and quality evaluation of groundwater suitability for domestic and agricultural uses in the state of Qatar
topic Engineering
Chemical engineering
Environmental sciences
Environmental biotechnology
Groundwater
Hydrogeochemical characterization
Domestic use
Agriculture use
Geochemical modeling
Geo-statistical analysis