Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production

<p>This study presents a comprehensive system integrating solar energy through a photovoltaic thermal (PV/T) unit to generate electricity and thermal energy. This energy powers an ejector cooling system and supports reverse osmosis (RO) desalination. Rejected brine from the RO process is treat...

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Main Author: Nadira Salsabila (16855101) (author)
Other Authors: Muhammad Usman Sajid (14778232) (author), Yusuf Bicer (14158977) (author)
Published: 2025
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author Nadira Salsabila (16855101)
author2 Muhammad Usman Sajid (14778232)
Yusuf Bicer (14158977)
author2_role author
author
author_facet Nadira Salsabila (16855101)
Muhammad Usman Sajid (14778232)
Yusuf Bicer (14158977)
author_role author
dc.creator.none.fl_str_mv Nadira Salsabila (16855101)
Muhammad Usman Sajid (14778232)
Yusuf Bicer (14158977)
dc.date.none.fl_str_mv 2025-01-07T03:00:00Z
dc.identifier.none.fl_str_mv 10.1016/j.ijhydene.2024.12.428
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Thermodynamic_analysis_of_solar-driven_integrated_system_for_efficient_brine_management_and_hydrogen_production/28194362
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Engineering
Electrical engineering
Electronics, sensors and digital hardware
Brine management
Freshwater
Hydrogen production
Renewable energy
Thermodynamic analysis
dc.title.none.fl_str_mv Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p>This study presents a comprehensive system integrating solar energy through a photovoltaic thermal (PV/T) unit to generate electricity and thermal energy. This energy powers an ejector cooling system and supports reverse osmosis (RO) desalination. Rejected brine from the RO process is treated using reverse electrodialysis (RED) and the photo-chloralkali (PCA) process to produce valuable chemicals, including hydrogen, which is converted into electricity using a proton exchange membrane (PEM) fuel cell. A detailed thermodynamic assessment is conducted, including energy, entropy, and exergy balances, alongside a parametric study to evaluate system performance and optimize input parameters. The results show that the system achieved energy and exergy efficiencies of 66.9% and 23.1%, respectively, with the PV/T subsystem showing the highest exergy destruction rate. The system produces 18.78 kg/day of hydrogen and 120.6 m³/day of freshwater. The RED system generates hydrogen at 0.00041 kg/s where the production rate increases with rising current density while the PCA system produces hydrogen at a rate of 0.00024 kg/s. The PEM fuel cell generates 4.9 kW of electricity, though its efficiency decreases with higher current density.</p><h2>Other Information</h2> <p> Published in: International Journal of Hydrogen Energy<br> License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.ijhydene.2024.12.428" target="_blank">https://dx.doi.org/10.1016/j.ijhydene.2024.12.428</a></p>
eu_rights_str_mv openAccess
id Manara2_c508b1a188ccd52dc685063dcf698108
identifier_str_mv 10.1016/j.ijhydene.2024.12.428
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/28194362
publishDate 2025
repository.mail.fl_str_mv
repository.name.fl_str_mv
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rights_invalid_str_mv CC BY 4.0
spelling Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen productionNadira Salsabila (16855101)Muhammad Usman Sajid (14778232)Yusuf Bicer (14158977)EngineeringElectrical engineeringElectronics, sensors and digital hardwareBrine managementFreshwaterHydrogen productionRenewable energyThermodynamic analysis<p>This study presents a comprehensive system integrating solar energy through a photovoltaic thermal (PV/T) unit to generate electricity and thermal energy. This energy powers an ejector cooling system and supports reverse osmosis (RO) desalination. Rejected brine from the RO process is treated using reverse electrodialysis (RED) and the photo-chloralkali (PCA) process to produce valuable chemicals, including hydrogen, which is converted into electricity using a proton exchange membrane (PEM) fuel cell. A detailed thermodynamic assessment is conducted, including energy, entropy, and exergy balances, alongside a parametric study to evaluate system performance and optimize input parameters. The results show that the system achieved energy and exergy efficiencies of 66.9% and 23.1%, respectively, with the PV/T subsystem showing the highest exergy destruction rate. The system produces 18.78 kg/day of hydrogen and 120.6 m³/day of freshwater. The RED system generates hydrogen at 0.00041 kg/s where the production rate increases with rising current density while the PCA system produces hydrogen at a rate of 0.00024 kg/s. The PEM fuel cell generates 4.9 kW of electricity, though its efficiency decreases with higher current density.</p><h2>Other Information</h2> <p> Published in: International Journal of Hydrogen Energy<br> License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.ijhydene.2024.12.428" target="_blank">https://dx.doi.org/10.1016/j.ijhydene.2024.12.428</a></p>2025-01-07T03:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.ijhydene.2024.12.428https://figshare.com/articles/journal_contribution/Thermodynamic_analysis_of_solar-driven_integrated_system_for_efficient_brine_management_and_hydrogen_production/28194362CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/281943622025-01-07T03:00:00Z
spellingShingle Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
Nadira Salsabila (16855101)
Engineering
Electrical engineering
Electronics, sensors and digital hardware
Brine management
Freshwater
Hydrogen production
Renewable energy
Thermodynamic analysis
status_str publishedVersion
title Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
title_full Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
title_fullStr Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
title_full_unstemmed Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
title_short Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
title_sort Thermodynamic analysis of solar-driven integrated system for efficient brine management and hydrogen production
topic Engineering
Electrical engineering
Electronics, sensors and digital hardware
Brine management
Freshwater
Hydrogen production
Renewable energy
Thermodynamic analysis