Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture
<p dir="ltr">Adsorption of carbon dioxide (CO<sub>2</sub>), as well as many other kinds of small molecules, is of importance for industrial and sensing applications. Metal-organic framework (MOF)-based adsorbents are spotlighted for such applications. An essential for MOF...
Saved in:
| Main Author: | |
|---|---|
| Other Authors: | , , , , , , , |
| Published: |
2022
|
| Subjects: | |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1864513519197618176 |
|---|---|
| author | Sifani Zavahir (1657531) |
| author2 | Hamdi Ben Yahia (9662822) Julian Schneider (1342149) DongSuk Han (18385035) Igor Krupa (1389267) Tausif Altamash (3846304) Mert Atilhan (1272906) Abdulkarem Amhamed (14778130) Peter Kasak (1360617) |
| author2_role | author author author author author author author author |
| author_facet | Sifani Zavahir (1657531) Hamdi Ben Yahia (9662822) Julian Schneider (1342149) DongSuk Han (18385035) Igor Krupa (1389267) Tausif Altamash (3846304) Mert Atilhan (1272906) Abdulkarem Amhamed (14778130) Peter Kasak (1360617) |
| author_role | author |
| dc.creator.none.fl_str_mv | Sifani Zavahir (1657531) Hamdi Ben Yahia (9662822) Julian Schneider (1342149) DongSuk Han (18385035) Igor Krupa (1389267) Tausif Altamash (3846304) Mert Atilhan (1272906) Abdulkarem Amhamed (14778130) Peter Kasak (1360617) |
| dc.date.none.fl_str_mv | 2022-06-15T03:00:00Z |
| dc.identifier.none.fl_str_mv | 10.3390/molecules27123845 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/Fluorescent_Zn_II_-Based_Metal-Organic_Framework_Interaction_with_Organic_Solvents_and_CO_sub_2_sub_and_Methane_Capture/25610202 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Biomedical and clinical sciences Pharmacology and pharmaceutical sciences Chemical sciences Analytical chemistry Organic chemistry MOF citric acid derivative TPDCA |
| dc.title.none.fl_str_mv | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p dir="ltr">Adsorption of carbon dioxide (CO<sub>2</sub>), as well as many other kinds of small molecules, is of importance for industrial and sensing applications. Metal-organic framework (MOF)-based adsorbents are spotlighted for such applications. An essential for MOF adsorbent application is a simple and easy fabrication process, preferably from a cheap, sustainable, and environmentally friendly ligand. Herein, we fabricated a novel structural, thermally stable MOF with fluorescence properties, namely Zn [5-oxo-2,3-dihydro-5H-[1,3]-thiazolo [3,2-a]pyridine-3,7-dicarboxylic acid (TPDCA)] • dimethylformamide (DMF) •0.25 H<sub>2</sub>O (coded as QUF-001 MOF), in solvothermal conditions by using zinc nitrate as a source of metal ion and TPDCA as a ligand easy accessible from citric acid and cysteine. Single crystal X-ray diffraction analysis and microscopic examination revealed the two-dimensional character of the formed MOF. Upon treatment of QUF-001 with organic solvents (such as methanol, isopropanol, chloroform, dimethylformamide, tetrahydrofuran, hexane), interactions were observed and changes in fluorescence maxima as well as in the powder diffraction patterns were noticed, indicating the inclusion and intercalation of the solvents into the interlamellar space of the crystal structure of QUF-001. Furthermore, CO<sub>2</sub> and CH<sub>4</sub> molecule sorption properties for QUF-001 reached up to 1.6 mmol/g and 8.1 mmol/g, respectively, at 298 K and a pressure of 50 bars.</p><p dir="ltr"><br></p><h2>Other Information</h2><p dir="ltr">Published in: Molecules<br>License: <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank">https://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.3390/molecules27123845" target="_blank">https://dx.doi.org/10.3390/molecules27123845</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_c8e3a3aefb472e2c524bea9b04601c97 |
| identifier_str_mv | 10.3390/molecules27123845 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/25610202 |
| publishDate | 2022 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane CaptureSifani Zavahir (1657531)Hamdi Ben Yahia (9662822)Julian Schneider (1342149)DongSuk Han (18385035)Igor Krupa (1389267)Tausif Altamash (3846304)Mert Atilhan (1272906)Abdulkarem Amhamed (14778130)Peter Kasak (1360617)Biomedical and clinical sciencesPharmacology and pharmaceutical sciencesChemical sciencesAnalytical chemistryOrganic chemistryMOFcitric acid derivativeTPDCA<p dir="ltr">Adsorption of carbon dioxide (CO<sub>2</sub>), as well as many other kinds of small molecules, is of importance for industrial and sensing applications. Metal-organic framework (MOF)-based adsorbents are spotlighted for such applications. An essential for MOF adsorbent application is a simple and easy fabrication process, preferably from a cheap, sustainable, and environmentally friendly ligand. Herein, we fabricated a novel structural, thermally stable MOF with fluorescence properties, namely Zn [5-oxo-2,3-dihydro-5H-[1,3]-thiazolo [3,2-a]pyridine-3,7-dicarboxylic acid (TPDCA)] • dimethylformamide (DMF) •0.25 H<sub>2</sub>O (coded as QUF-001 MOF), in solvothermal conditions by using zinc nitrate as a source of metal ion and TPDCA as a ligand easy accessible from citric acid and cysteine. Single crystal X-ray diffraction analysis and microscopic examination revealed the two-dimensional character of the formed MOF. Upon treatment of QUF-001 with organic solvents (such as methanol, isopropanol, chloroform, dimethylformamide, tetrahydrofuran, hexane), interactions were observed and changes in fluorescence maxima as well as in the powder diffraction patterns were noticed, indicating the inclusion and intercalation of the solvents into the interlamellar space of the crystal structure of QUF-001. Furthermore, CO<sub>2</sub> and CH<sub>4</sub> molecule sorption properties for QUF-001 reached up to 1.6 mmol/g and 8.1 mmol/g, respectively, at 298 K and a pressure of 50 bars.</p><p dir="ltr"><br></p><h2>Other Information</h2><p dir="ltr">Published in: Molecules<br>License: <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank">https://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.3390/molecules27123845" target="_blank">https://dx.doi.org/10.3390/molecules27123845</a></p>2022-06-15T03:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.3390/molecules27123845https://figshare.com/articles/journal_contribution/Fluorescent_Zn_II_-Based_Metal-Organic_Framework_Interaction_with_Organic_Solvents_and_CO_sub_2_sub_and_Methane_Capture/25610202CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/256102022022-06-15T03:00:00Z |
| spellingShingle | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture Sifani Zavahir (1657531) Biomedical and clinical sciences Pharmacology and pharmaceutical sciences Chemical sciences Analytical chemistry Organic chemistry MOF citric acid derivative TPDCA |
| status_str | publishedVersion |
| title | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture |
| title_full | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture |
| title_fullStr | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture |
| title_full_unstemmed | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture |
| title_short | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture |
| title_sort | Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO<sub>2</sub> and Methane Capture |
| topic | Biomedical and clinical sciences Pharmacology and pharmaceutical sciences Chemical sciences Analytical chemistry Organic chemistry MOF citric acid derivative TPDCA |