Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS
<h3>Background</h3><p dir="ltr">Bioenergy attracts much attention due to the global demand for renewable and sustainable energy resources. Waste biomass feedstocks—date pits, coffee waste, and cow dung—require efficient and environmentally friendly waste-management techno...
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2022
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| _version_ | 1864513507033088000 |
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| author | Sabah Mariyam (14150859) |
| author2 | Mohammad Alherbawi (14155767) Naim Rashid (15044240) Tareq Al-Ansari (9872268) Gordon McKay (1755814) |
| author2_role | author author author author |
| author_facet | Sabah Mariyam (14150859) Mohammad Alherbawi (14155767) Naim Rashid (15044240) Tareq Al-Ansari (9872268) Gordon McKay (1755814) |
| author_role | author |
| dc.creator.none.fl_str_mv | Sabah Mariyam (14150859) Mohammad Alherbawi (14155767) Naim Rashid (15044240) Tareq Al-Ansari (9872268) Gordon McKay (1755814) |
| dc.date.none.fl_str_mv | 2022-10-09T03:00:00Z |
| dc.identifier.none.fl_str_mv | 10.3390/en15197409 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/Bio-Oil_Production_from_Multi-Waste_Biomass_Co-Pyrolysis_Using_Analytical_Py_GC_MS/26840092 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Engineering Chemical engineering Environmental engineering Py–GC/MS fast pyrolysis bio-oil TGA biomass |
| dc.title.none.fl_str_mv | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <h3>Background</h3><p dir="ltr">Bioenergy attracts much attention due to the global demand for renewable and sustainable energy resources. Waste biomass feedstocks—date pits, coffee waste, and cow dung—require efficient and environmentally friendly waste-management technologies such as pyrolysis. Fast pyrolysis occurs at fast heating rates (10–100 °C/s), generates high bio-oil yields, and is the most widely used process for biofuel generation. The aim of the study is to compare the effect of pyrolysis between single, binary, and ternary feeds on thermal degradation behavior and bio-oil composition. </p><h3>Methods</h3><p dir="ltr">Thermogravimetric analysis (TGA) was conducted at 30 °C/min from room temperature to 850 °C to understand the thermal degradation behavior of the biomasses. A Pyroprobe® reactor—a micro-scale pyrolyzer—was used to conduct the fast pyrolysis at 500 °C with a heating rate of 10 °C/s, and the volatile contents were quantified using a gas chromatograph–mass spectrometer (GC/MS). </p><h3>Results</h3><p dir="ltr">The (TGA) showed three main stages of decomposition following dehydration, devolatilization, and char degradation for the different single and multiple feeds. According to the identified compounds, the bio-oil components are broadly identified as aldehydes, amines, aliphatic, aromatics, alcohols, furans, ketones, and acids. The three single-biomass pyrolysis products have four compounds in common, acetic acid and ketone groups (acetic acid, 2-propanone, 1-hydroxy-, benzyl methyl ketone, and 1,2-cyclopentanedione). </p><h3>Conclusion</h3><p dir="ltr"> The bio-oil generated from the feeds comprises great potential for volatiles, diesel, and gasoline production with carbon atoms ranging from C2–C33. Future studies should focus on understanding the effect of procedural parameters, including blending ratio, temperature, and heating rates, on bio-oil composition. Additional molecular techniques should be employed to understand biomass components’ reaction mechanisms to produce useful bio-oil products.</p><h2>Other Information</h2><p dir="ltr">Published in: Energies<br>License: <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank">https://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.3390/en15197409" target="_blank">https://dx.doi.org/10.3390/en15197409</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_ceb7202c7ea598d3552d2b8fa6e66c28 |
| identifier_str_mv | 10.3390/en15197409 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/26840092 |
| publishDate | 2022 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MSSabah Mariyam (14150859)Mohammad Alherbawi (14155767)Naim Rashid (15044240)Tareq Al-Ansari (9872268)Gordon McKay (1755814)EngineeringChemical engineeringEnvironmental engineeringPy–GC/MSfast pyrolysisbio-oilTGAbiomass<h3>Background</h3><p dir="ltr">Bioenergy attracts much attention due to the global demand for renewable and sustainable energy resources. Waste biomass feedstocks—date pits, coffee waste, and cow dung—require efficient and environmentally friendly waste-management technologies such as pyrolysis. Fast pyrolysis occurs at fast heating rates (10–100 °C/s), generates high bio-oil yields, and is the most widely used process for biofuel generation. The aim of the study is to compare the effect of pyrolysis between single, binary, and ternary feeds on thermal degradation behavior and bio-oil composition. </p><h3>Methods</h3><p dir="ltr">Thermogravimetric analysis (TGA) was conducted at 30 °C/min from room temperature to 850 °C to understand the thermal degradation behavior of the biomasses. A Pyroprobe® reactor—a micro-scale pyrolyzer—was used to conduct the fast pyrolysis at 500 °C with a heating rate of 10 °C/s, and the volatile contents were quantified using a gas chromatograph–mass spectrometer (GC/MS). </p><h3>Results</h3><p dir="ltr">The (TGA) showed three main stages of decomposition following dehydration, devolatilization, and char degradation for the different single and multiple feeds. According to the identified compounds, the bio-oil components are broadly identified as aldehydes, amines, aliphatic, aromatics, alcohols, furans, ketones, and acids. The three single-biomass pyrolysis products have four compounds in common, acetic acid and ketone groups (acetic acid, 2-propanone, 1-hydroxy-, benzyl methyl ketone, and 1,2-cyclopentanedione). </p><h3>Conclusion</h3><p dir="ltr"> The bio-oil generated from the feeds comprises great potential for volatiles, diesel, and gasoline production with carbon atoms ranging from C2–C33. Future studies should focus on understanding the effect of procedural parameters, including blending ratio, temperature, and heating rates, on bio-oil composition. Additional molecular techniques should be employed to understand biomass components’ reaction mechanisms to produce useful bio-oil products.</p><h2>Other Information</h2><p dir="ltr">Published in: Energies<br>License: <a href="https://creativecommons.org/licenses/by/4.0/" target="_blank">https://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.3390/en15197409" target="_blank">https://dx.doi.org/10.3390/en15197409</a></p>2022-10-09T03:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.3390/en15197409https://figshare.com/articles/journal_contribution/Bio-Oil_Production_from_Multi-Waste_Biomass_Co-Pyrolysis_Using_Analytical_Py_GC_MS/26840092CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/268400922022-10-09T03:00:00Z |
| spellingShingle | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS Sabah Mariyam (14150859) Engineering Chemical engineering Environmental engineering Py–GC/MS fast pyrolysis bio-oil TGA biomass |
| status_str | publishedVersion |
| title | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS |
| title_full | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS |
| title_fullStr | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS |
| title_full_unstemmed | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS |
| title_short | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS |
| title_sort | Bio-Oil Production from Multi-Waste Biomass Co-Pyrolysis Using Analytical Py–GC/MS |
| topic | Engineering Chemical engineering Environmental engineering Py–GC/MS fast pyrolysis bio-oil TGA biomass |