Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85)
<p dir="ltr">The new members of the Ag<sub>2−</sub><sub>x</sub>Na<sub>x</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (0 ≤ x ≤ 2) solid solution were synthesized by a solid-state reaction route. The crystal str...
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2019
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| _version_ | 1864513559024631808 |
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| author | Hamdi Ben Yahia (14579467) |
| author2 | Masahiro Shikano (10495128) |
| author2_role | author |
| author_facet | Hamdi Ben Yahia (14579467) Masahiro Shikano (10495128) |
| author_role | author |
| dc.creator.none.fl_str_mv | Hamdi Ben Yahia (14579467) Masahiro Shikano (10495128) |
| dc.date.none.fl_str_mv | 2019-08-29T00:00:00Z |
| dc.identifier.none.fl_str_mv | 10.1515/znb-2019-0116 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/Structural_properties_of_the_alluaudite-type_materials_Ag_sub_2_sub_i_sub_x_sub_Na_sub_x_sub_i_Mn_sub_3_sub_VO_sub_4_sub_sub_3_sub_i_x_i_0_62_and_1_85_/22035101 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Chemical sciences Inorganic chemistry crystal structure solid solution vanadate |
| dc.title.none.fl_str_mv | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p dir="ltr">The new members of the Ag<sub>2−</sub><sub>x</sub>Na<sub>x</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (0 ≤ x ≤ 2) solid solution were synthesized by a solid-state reaction route. The crystal structures of Ag<sub>1.38</sub>Na<sub>0.62</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (x = 0.62) and Ag<sub>0.15</sub>Na<sub>1.85</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (x = 1.85) were solved using single crystal X-ray diffraction. These phases crystallize with a monoclinic symmetry (space group C2/c), and their structures are new members of the well-known alluaudite family. In both compounds, the Ag<sup>+</sup>/Na<sup>+</sup>, Mn<sup>2+</sup>/Mn<sup>3+</sup> and V<sup>5+</sup> cations are eight-, six-, and four-coordinated to oxygen atoms, respectively. All the atoms are perfectly ordered except for the Ag and Na atoms which are statistically disordered over a 4b and a 4e atomic position. This single-crystal structural study confirms the existence of a full solid solution Ag<sub>2−</sub><sub>x</sub>Na<sub>x</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (0 ≤ x ≤ 1.85).</p><h2>Other information</h2><p dir="ltr">Published in: Zeitschrift für Naturforschung B<br>License: <a href="http://creativecommons.org/licenses/by/4.0" target="_blank">http://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1515/znb-2019-0116" target="_blank">http://dx.doi.org/10.1515/znb-2019-0116</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_d62d3f54f2c6e7679f9b8dc4f447e2c2 |
| identifier_str_mv | 10.1515/znb-2019-0116 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/22035101 |
| publishDate | 2019 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85)Hamdi Ben Yahia (14579467)Masahiro Shikano (10495128)Chemical sciencesInorganic chemistrycrystal structuresolid solutionvanadate<p dir="ltr">The new members of the Ag<sub>2−</sub><sub>x</sub>Na<sub>x</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (0 ≤ x ≤ 2) solid solution were synthesized by a solid-state reaction route. The crystal structures of Ag<sub>1.38</sub>Na<sub>0.62</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (x = 0.62) and Ag<sub>0.15</sub>Na<sub>1.85</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (x = 1.85) were solved using single crystal X-ray diffraction. These phases crystallize with a monoclinic symmetry (space group C2/c), and their structures are new members of the well-known alluaudite family. In both compounds, the Ag<sup>+</sup>/Na<sup>+</sup>, Mn<sup>2+</sup>/Mn<sup>3+</sup> and V<sup>5+</sup> cations are eight-, six-, and four-coordinated to oxygen atoms, respectively. All the atoms are perfectly ordered except for the Ag and Na atoms which are statistically disordered over a 4b and a 4e atomic position. This single-crystal structural study confirms the existence of a full solid solution Ag<sub>2−</sub><sub>x</sub>Na<sub>x</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (0 ≤ x ≤ 1.85).</p><h2>Other information</h2><p dir="ltr">Published in: Zeitschrift für Naturforschung B<br>License: <a href="http://creativecommons.org/licenses/by/4.0" target="_blank">http://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1515/znb-2019-0116" target="_blank">http://dx.doi.org/10.1515/znb-2019-0116</a></p>2019-08-29T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1515/znb-2019-0116https://figshare.com/articles/journal_contribution/Structural_properties_of_the_alluaudite-type_materials_Ag_sub_2_sub_i_sub_x_sub_Na_sub_x_sub_i_Mn_sub_3_sub_VO_sub_4_sub_sub_3_sub_i_x_i_0_62_and_1_85_/22035101CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/220351012019-08-29T00:00:00Z |
| spellingShingle | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) Hamdi Ben Yahia (14579467) Chemical sciences Inorganic chemistry crystal structure solid solution vanadate |
| status_str | publishedVersion |
| title | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) |
| title_full | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) |
| title_fullStr | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) |
| title_full_unstemmed | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) |
| title_short | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) |
| title_sort | Structural properties of the alluaudite-type materials Ag<sub>2–</sub><i><sub>x</sub>Na<sub>x</sub></i>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub> (<i>x</i>=0.62 and 1.85) |
| topic | Chemical sciences Inorganic chemistry crystal structure solid solution vanadate |