Up-cycling plastic waste into swellable super-sorbents

<p dir="ltr">Environmental pollution caused by plastic waste and oil spills has emerged as a major concern in recent years. Consequently, there has been a growing interest in exploring innovative solutions to address these challenges. Herein, we report a method to upcycle polyolefins...

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Main Author: Junaid Saleem (14670322) (author)
Other Authors: Zubair Khalid Baig Moghal (16489225) (author), Gordon McKay (1755814) (author)
Published: 2023
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Summary:<p dir="ltr">Environmental pollution caused by plastic waste and oil spills has emerged as a major concern in recent years. Consequently, there has been a growing interest in exploring innovative solutions to address these challenges. Herein, we report a method to upcycle polyolefins-based plastic waste by converting it into a bimodal superoleophilic sorbent using dissolution, spin-coating, and annealing techniques. The resulting sorbent possesses an extensive network of pores and cavities with a size range from 0.5 to 5 µm and 150–200 µm, respectively, with an average of 600 cavities per cm<sup>2</sup>. Each cavity can swell up to twenty times the thickness of the sorbent, exhibiting sponge-like behavior. The sorbent had an oil uptake capacity of 70–140 g/g, depending on the type of sorbate and dripping time. Moreover, the sorbent can be mechanically or manually squeezed to recover the sorbed oil. Our integrated methodology provides a promising approach to upcycling plastic waste as an abundant source of value-added materials.</p><h2>Other Information</h2><p dir="ltr">Published in: Journal of Hazardous Materials<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1016/j.jhazmat.2023.131356" target="_blank">http://dx.doi.org/10.1016/j.jhazmat.2023.131356</a></p>