Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide
<p dir="ltr">The redox reactivity of the Li-, Mg-, Ca-, Sr-, Ba-, and Sn-doped ceria (Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub>) toward thermochemical CO<sub>2</sub> splitting is investigated. Proposed Ce<...
محفوظ في:
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| مؤلفون آخرون: | , , , , |
| منشور في: |
2022
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| الموضوعات: | |
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إضافة وسم
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| _version_ | 1864513567631343616 |
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| author | Gorakshnath Takalkar (14151135) |
| author2 | Rahul R. Bhosale (6467102) Suliman Rashid (14151138) Fares AlMomani (14097725) Rana Abdul Shakoor (14151141) Abdullah Al Ashraf (14151144) |
| author2_role | author author author author author |
| author_facet | Gorakshnath Takalkar (14151135) Rahul R. Bhosale (6467102) Suliman Rashid (14151138) Fares AlMomani (14097725) Rana Abdul Shakoor (14151141) Abdullah Al Ashraf (14151144) |
| author_role | author |
| dc.creator.none.fl_str_mv | Gorakshnath Takalkar (14151135) Rahul R. Bhosale (6467102) Suliman Rashid (14151138) Fares AlMomani (14097725) Rana Abdul Shakoor (14151141) Abdullah Al Ashraf (14151144) |
| dc.date.none.fl_str_mv | 2022-11-22T21:13:28Z |
| dc.identifier.none.fl_str_mv | 10.1007/s10853-020-04875-1 |
| dc.relation.none.fl_str_mv | https://figshare.com/articles/journal_contribution/Application_of_Li-_Mg-_Ba-_Sr-_Ca-_and_Sn-doped_ceria_for_solar-driven_thermochemical_conversion_of_carbon_dioxide/21597309 |
| dc.rights.none.fl_str_mv | CC BY 4.0 info:eu-repo/semantics/openAccess |
| dc.subject.none.fl_str_mv | Engineering Materials engineering Mechanical engineering Ceria-based materials Doped ceria (Ce0.9A0.1O2−δ) Redox reactivity Thermochemical CO₂ splitting |
| dc.title.none.fl_str_mv | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide |
| dc.type.none.fl_str_mv | Text Journal contribution info:eu-repo/semantics/publishedVersion text contribution to journal |
| description | <p dir="ltr">The redox reactivity of the Li-, Mg-, Ca-, Sr-, Ba-, and Sn-doped ceria (Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub>) toward thermochemical CO<sub>2</sub> splitting is investigated. Proposed Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> materials are prepared via co-precipitation of the hydroxide technique. The composition, morphology, and the average particle size of the Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> materials are determined by using suitable characterization methods. By utilizing a thermogravimetric analyzer setup, the long-term redox performance of each Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> material is estimated. The results obtained indicate that all the Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> materials are able to produce steady amounts of O<sub>2</sub> and CO from cycle 4 to cycle 10. Based on the average <i>n</i><sub><em>O2</em></sub> released and n<sub><em>CO</em></sub> produced, the Ce<sub>0.899</sub>Sn<sub>0.102O2.002</sub> and Ce<sub>0.895Ca0.099O1.889</sub> are observed to be the top and bottom-most choices. When compared with the CeO<sub>2</sub> material, all Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub>materials showed elevated levels of O<sub>2</sub> release and CO production.</p><h2>Other Information</h2><p dir="ltr">Published in: Journal of Materials Science<br>License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1007/s10853-020-04875-1" target="_blank">http://dx.doi.org/10.1007/s10853-020-04875-1</a></p> |
| eu_rights_str_mv | openAccess |
| id | Manara2_daba7aa27a10f5f2fb6239d84a7fc83a |
| identifier_str_mv | 10.1007/s10853-020-04875-1 |
| network_acronym_str | Manara2 |
| network_name_str | Manara2 |
| oai_identifier_str | oai:figshare.com:article/21597309 |
| publishDate | 2022 |
| repository.mail.fl_str_mv | |
| repository.name.fl_str_mv | |
| repository_id_str | |
| rights_invalid_str_mv | CC BY 4.0 |
| spelling | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxideGorakshnath Takalkar (14151135)Rahul R. Bhosale (6467102)Suliman Rashid (14151138)Fares AlMomani (14097725)Rana Abdul Shakoor (14151141)Abdullah Al Ashraf (14151144)EngineeringMaterials engineeringMechanical engineeringCeria-based materialsDoped ceria (Ce0.9A0.1O2−δ)Redox reactivityThermochemicalCO₂ splitting<p dir="ltr">The redox reactivity of the Li-, Mg-, Ca-, Sr-, Ba-, and Sn-doped ceria (Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub>) toward thermochemical CO<sub>2</sub> splitting is investigated. Proposed Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> materials are prepared via co-precipitation of the hydroxide technique. The composition, morphology, and the average particle size of the Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> materials are determined by using suitable characterization methods. By utilizing a thermogravimetric analyzer setup, the long-term redox performance of each Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> material is estimated. The results obtained indicate that all the Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub> materials are able to produce steady amounts of O<sub>2</sub> and CO from cycle 4 to cycle 10. Based on the average <i>n</i><sub><em>O2</em></sub> released and n<sub><em>CO</em></sub> produced, the Ce<sub>0.899</sub>Sn<sub>0.102O2.002</sub> and Ce<sub>0.895Ca0.099O1.889</sub> are observed to be the top and bottom-most choices. When compared with the CeO<sub>2</sub> material, all Ce<sub>0.9</sub>A0.<sub>1</sub>O<sub>2</sub>−<sub>δ</sub>materials showed elevated levels of O<sub>2</sub> release and CO production.</p><h2>Other Information</h2><p dir="ltr">Published in: Journal of Materials Science<br>License: <a href="https://creativecommons.org/licenses/by/4.0" target="_blank">https://creativecommons.org/licenses/by/4.0</a><br>See article on publisher's website: <a href="http://dx.doi.org/10.1007/s10853-020-04875-1" target="_blank">http://dx.doi.org/10.1007/s10853-020-04875-1</a></p>2022-11-22T21:13:28ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1007/s10853-020-04875-1https://figshare.com/articles/journal_contribution/Application_of_Li-_Mg-_Ba-_Sr-_Ca-_and_Sn-doped_ceria_for_solar-driven_thermochemical_conversion_of_carbon_dioxide/21597309CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/215973092022-11-22T21:13:28Z |
| spellingShingle | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide Gorakshnath Takalkar (14151135) Engineering Materials engineering Mechanical engineering Ceria-based materials Doped ceria (Ce0.9A0.1O2−δ) Redox reactivity Thermochemical CO₂ splitting |
| status_str | publishedVersion |
| title | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide |
| title_full | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide |
| title_fullStr | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide |
| title_full_unstemmed | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide |
| title_short | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide |
| title_sort | Application of Li-, Mg-, Ba-, Sr-, Ca-, and Sn-doped ceria for solar-driven thermochemical conversion of carbon dioxide |
| topic | Engineering Materials engineering Mechanical engineering Ceria-based materials Doped ceria (Ce0.9A0.1O2−δ) Redox reactivity Thermochemical CO₂ splitting |