Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study

<p dir="ltr">This work presents a comparative evaluation of two distinct fuels, methanol and hydrogen, production and power generation routes via fuel cells. The first route includes the methanol production from direct partial oxidation of methane to methanol using solar energy, wher...

Full description

Saved in:
Bibliographic Details
Main Author: Amira Chebbi (19756983) (author)
Other Authors: Yusuf Bicer (14158977) (author)
Published: 2024
Subjects:
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1864513555986907136
author Amira Chebbi (19756983)
author2 Yusuf Bicer (14158977)
author2_role author
author_facet Amira Chebbi (19756983)
Yusuf Bicer (14158977)
author_role author
dc.creator.none.fl_str_mv Amira Chebbi (19756983)
Yusuf Bicer (14158977)
dc.date.none.fl_str_mv 2024-10-01T00:00:00Z
dc.identifier.none.fl_str_mv 10.1016/j.tsep.2024.102911
dc.relation.none.fl_str_mv https://figshare.com/articles/journal_contribution/Thermodynamic_evaluation_of_solar_energy-based_methanol_and_hydrogen_production_and_power_generation_pathways_A_comparative_study/27130071
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Engineering
Chemical engineering
Electrical engineering
Concentrated solar energy
Methane conversion
Hydrogen fuel cell
Hydrogen storage
Methanol fuel cell
Partial oxidation of methane
dc.title.none.fl_str_mv Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
dc.type.none.fl_str_mv Text
Journal contribution
info:eu-repo/semantics/publishedVersion
text
contribution to journal
description <p dir="ltr">This work presents a comparative evaluation of two distinct fuels, methanol and hydrogen, production and power generation routes via fuel cells. The first route includes the methanol production from direct partial oxidation of methane to methanol using solar energy, where the methanol is condensed, stored, and sent to a direct methanol fuel cell. The second route is hydrogen production from solar methane cracking (named as turquoise hydrogen), where heat is supplied from concentrated solar power, and hydrogen is stored and directed to a hydrogen fuel cell. This study aims to provide insights into these fuels' production conditions, storage methods, energy, and exergy efficiencies. The proposed system is simulated using the Engineering Equation Solver software, and a thermodynamic analysis of the entire system, including all the equipment and process streams, is performed. The methanol and hydrogen route’s overall energy and exergy efficiencies are 39.75 %, 38.35 %, 34.21 %, and 33 %, respectively. The highest exergy destruction rate of 1605 kW is observed for the partial oxidation of methane to methanol. The methanol and hydrogen routes generate 32.087 MWh and 11.582 MWh of electricity for 16-hour of fuel cell operation for the same amount of methane feedstock, respectively. Sensitivity analysis has been performed to observe the effects of different parameters, such as operating temperature and mass flow rate of fuels, on the electricity production and energy efficiencies of the systems.</p><h2>Other Information</h2><p dir="ltr">Published in: Thermal Science and Engineering Progress<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.tsep.2024.102911" target="_blank">https://dx.doi.org/10.1016/j.tsep.2024.102911</a></p>
eu_rights_str_mv openAccess
id Manara2_e8081b5dde785d4cbf94c9b817613467
identifier_str_mv 10.1016/j.tsep.2024.102911
network_acronym_str Manara2
network_name_str Manara2
oai_identifier_str oai:figshare.com:article/27130071
publishDate 2024
repository.mail.fl_str_mv
repository.name.fl_str_mv
repository_id_str
rights_invalid_str_mv CC BY 4.0
spelling Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative studyAmira Chebbi (19756983)Yusuf Bicer (14158977)EngineeringChemical engineeringElectrical engineeringConcentrated solar energyMethane conversionHydrogen fuel cellHydrogen storageMethanol fuel cellPartial oxidation of methane<p dir="ltr">This work presents a comparative evaluation of two distinct fuels, methanol and hydrogen, production and power generation routes via fuel cells. The first route includes the methanol production from direct partial oxidation of methane to methanol using solar energy, where the methanol is condensed, stored, and sent to a direct methanol fuel cell. The second route is hydrogen production from solar methane cracking (named as turquoise hydrogen), where heat is supplied from concentrated solar power, and hydrogen is stored and directed to a hydrogen fuel cell. This study aims to provide insights into these fuels' production conditions, storage methods, energy, and exergy efficiencies. The proposed system is simulated using the Engineering Equation Solver software, and a thermodynamic analysis of the entire system, including all the equipment and process streams, is performed. The methanol and hydrogen route’s overall energy and exergy efficiencies are 39.75 %, 38.35 %, 34.21 %, and 33 %, respectively. The highest exergy destruction rate of 1605 kW is observed for the partial oxidation of methane to methanol. The methanol and hydrogen routes generate 32.087 MWh and 11.582 MWh of electricity for 16-hour of fuel cell operation for the same amount of methane feedstock, respectively. Sensitivity analysis has been performed to observe the effects of different parameters, such as operating temperature and mass flow rate of fuels, on the electricity production and energy efficiencies of the systems.</p><h2>Other Information</h2><p dir="ltr">Published in: Thermal Science and Engineering Progress<br>License: <a href="http://creativecommons.org/licenses/by/4.0/" target="_blank">http://creativecommons.org/licenses/by/4.0/</a><br>See article on publisher's website: <a href="https://dx.doi.org/10.1016/j.tsep.2024.102911" target="_blank">https://dx.doi.org/10.1016/j.tsep.2024.102911</a></p>2024-10-01T00:00:00ZTextJournal contributioninfo:eu-repo/semantics/publishedVersiontextcontribution to journal10.1016/j.tsep.2024.102911https://figshare.com/articles/journal_contribution/Thermodynamic_evaluation_of_solar_energy-based_methanol_and_hydrogen_production_and_power_generation_pathways_A_comparative_study/27130071CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/271300712024-10-01T00:00:00Z
spellingShingle Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
Amira Chebbi (19756983)
Engineering
Chemical engineering
Electrical engineering
Concentrated solar energy
Methane conversion
Hydrogen fuel cell
Hydrogen storage
Methanol fuel cell
Partial oxidation of methane
status_str publishedVersion
title Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
title_full Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
title_fullStr Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
title_full_unstemmed Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
title_short Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
title_sort Thermodynamic evaluation of solar energy-based methanol and hydrogen production and power generation pathways: A comparative study
topic Engineering
Chemical engineering
Electrical engineering
Concentrated solar energy
Methane conversion
Hydrogen fuel cell
Hydrogen storage
Methanol fuel cell
Partial oxidation of methane