Chemical and Electrochemical Investigation of the Oxidation of a Highly Reduced Fe6C Iron Carbide Carbonyl Cluster: A Synthetic Route to Heteroleptic Fe6C and Fe5C Clusters

A chemical and electrochemical investigation of the redox chemistry of [Fe6C(CO)15]4– is reported and supported by computational studies. Depending on the experimental conditions, the original Fe6C cage is re...

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Main Author:	Tiziana Funaioli (249029) (author)
Other Authors:	Cristiana Cesari (1569862) (author), Beatrice Berti (5367962) (author), Marco Bortoluzzi (1431604) (author), Cristina Femoni (1692355) (author), Francesca Forti (89991) (author), Maria Carmela Iapalucci (1970383) (author), Giorgia Scorzoni (21252596) (author), Stefano Zacchini (1431607) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Microbiology Physiology Pharmacology Ecology Cancer Virology Computational Biology Environmental Sciences not elsewhere classified Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified phosphine ligand produces partial oxidative degradation dft calculations suggest 4 –</ sup 3 –</ sup 2 –</ sup 7 </ sub 6 </ sub 5 </ sub 3 </ sub 2 </ sub eec pathway also highly reduced fe fe ][ pf reverse electrochemical process co )< sub eec mechanism original fe heteroleptic fe synthetic route structurally characterized spectroelectrochemical methods redox chemistry partially degraded new clusters new carbonate heteroleptic species experimental conditions electrochemical investigation electrochemical findings e .</ computational studies computational outcomes computational methods carbide cluster acylating agents >, reduction
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Chemical and Electrochemical Investigation of the Oxidation of a Highly Reduced Fe<sub>6</sub>C Iron Carbide Carbonyl Cluster: A Synthetic Route to Heteroleptic Fe<sub>6</sub>C and Fe<sub>5</sub>C Clusters

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