Perovskite Solar Cells Made by a Self-Quenching Method Using a Volatile Perovskite Ink with Safer Alternatives to 2‑Methoxyethanol

Four solvents from the glycol ether (GE) family were evaluated as safer alternatives to the highly toxic 2-methoxyethanol (2ME) used for the fabrication of perovskite solar cells (PSCs). A self-quenching process by spin-coating the acetonitrile (ACN)-based ink for 7 s was developed. The influence of...

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Main Author: Samy Almosni (8345985) (author)
Other Authors: Fumiyasu Awai (8345988) (author), Ajay Jena (20419026) (author), Ludmila Cojocaru (4514701) (author), Ryota Kan (8996580) (author), Linh Vu Tuy (20419029) (author), Keishi Tada (11009254) (author), Kazuteru Nonomura (1930903) (author), Jotaro Nakazaki (1283088) (author), Satoshi Uchida (281774) (author), Hiroshi Segawa (1277808) (author)
Published: 2024
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Summary:Four solvents from the glycol ether (GE) family were evaluated as safer alternatives to the highly toxic 2-methoxyethanol (2ME) used for the fabrication of perovskite solar cells (PSCs). A self-quenching process by spin-coating the acetonitrile (ACN)-based ink for 7 s was developed. The influence of the ACN:GE ratio on the coverage of perovskite layers and cell efficiency was investigated to find that with the ACN:GE ratio of 8:1 the four solvents studied here can produce PSCs with an efficiency similar to 2ME and therefore can be used as a replacement for the latter.