Flash Communication: Strained and Bimetallic Structures of Rhodium and Iridium Germyl Complexes with Phosphinoamido Ligands

Flash Communication: Strained and Bimetallic Structures of Rhodium and Iridium Germyl Complexes with Phosphinoamido Ligands

In the coordination chemistry of heavier tetrylenes (:ER<sub>2</sub>, where E = Si, Ge, Sn, Pb), chelating P,N-donor ligands occupy a privileged position, though phosphinoamido ligands, [R<sub>2</sub>P–NR′]<sup>−</sup>, have been barely investigated. Herein, we re...

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Autore principale:	Sonia Bajo (1712881) (author)
Altri autori:	Marta Fernández-Buenestado (22684980) (author), Joaquín López-Serrano (1522171) (author), Jesús Campos (1366185) (author)
Pubblicazione:	2025
Soggetti:	Biophysics Biochemistry Medicine Cell Biology Physiology Space Science Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified computational studies support cod )]< sub 5 </ sub 2 </ sub iridium germyl complexes donor ligands occupy though phosphinoamido ligands cp *]< sub phosphinoamido ligands donor character chloride ligands phosphinoamido germylenes two metals structures confirmed structural characterization spectroscopically characterized significant π ray diffraction privileged position preparative scale new compounds flash communication coordination chemistry broken apart bimetallic structures barely investigated
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