Unconventional Pathways in Nitrogen-Centered SN2 Reactions: From Roundabout to Hydride Transfer

The mechanisms and dynamics of bimolecular nucleophilic substitution (SN2) reactions are complex and influenced by the nature of the central atom. In this study, we explore SN2 at a nitrogen center (SN2@N) by investigating the reac...

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Bibliographic Details
Main Author:	Siddharth Sankar Dutta (20293126) (author)
Other Authors:	Upakarasamy Lourderaj (2480632) (author)
Published:	2024
Subjects:	Biochemistry Microbiology Infectious Diseases Plant Biology Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified traditional direct rebound sup >–</ sup fc )/ aug bimolecular nucleophilic substitution transfer pathway leading 3 </ sub 2 </ sub roundabout pathways alongside n </ sub 2 product formation unconventional pathways hydride transfer umbrella inversion quantitative agreement pvdz level novel hydride methoxide ion group resulting experimental data energy proton central atom
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Unconventional Pathways in Nitrogen-Centered S<sub>N</sub>2 Reactions: From Roundabout to Hydride Transfer

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