Size-exclusion chromatography analysis of purified NagS.

<p>Analytical gel-filtration chromatography was performed on a Superdex 200 10/300 GL column (Cytiva) equilibrated with buffer containing 20 mM HEPES pH 7.5, 300 mM NaCl, 5% glycerol, and 1 mM DTT. NagS was analyzed at two protein concentrations (35 μM and 70 μM). Elution volumes (V<sub>...

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Main Author: Chao Li (145513) (author)
Other Authors: Mia Urem (22683580) (author), Ioli Kotsogianni (9930187) (author), Josephine Lau (20442343) (author), Chao Du (288036) (author), Somayah S. Elsayed (9192571) (author), Nathaniel I. Martin (847378) (author), Iain W. McNae (840777) (author), Patrick Voskamp (2311429) (author), Christoph Mayer (57204) (author), Sébastien Rigali (724082) (author), Navraj Pannu (10163763) (author), Jan Pieter Abrahams (1429531) (author), Lennart Schada von Borzyskowski (22683583) (author), Gilles P. van Wezel (7838948) (author)
Published: 2025
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_version_ 1849927625880895488
author Chao Li (145513)
author2 Mia Urem (22683580)
Ioli Kotsogianni (9930187)
Josephine Lau (20442343)
Chao Du (288036)
Somayah S. Elsayed (9192571)
Nathaniel I. Martin (847378)
Iain W. McNae (840777)
Patrick Voskamp (2311429)
Christoph Mayer (57204)
Sébastien Rigali (724082)
Navraj Pannu (10163763)
Jan Pieter Abrahams (1429531)
Lennart Schada von Borzyskowski (22683583)
Gilles P. van Wezel (7838948)
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
author
author_facet Chao Li (145513)
Mia Urem (22683580)
Ioli Kotsogianni (9930187)
Josephine Lau (20442343)
Chao Du (288036)
Somayah S. Elsayed (9192571)
Nathaniel I. Martin (847378)
Iain W. McNae (840777)
Patrick Voskamp (2311429)
Christoph Mayer (57204)
Sébastien Rigali (724082)
Navraj Pannu (10163763)
Jan Pieter Abrahams (1429531)
Lennart Schada von Borzyskowski (22683583)
Gilles P. van Wezel (7838948)
author_role author
dc.creator.none.fl_str_mv Chao Li (145513)
Mia Urem (22683580)
Ioli Kotsogianni (9930187)
Josephine Lau (20442343)
Chao Du (288036)
Somayah S. Elsayed (9192571)
Nathaniel I. Martin (847378)
Iain W. McNae (840777)
Patrick Voskamp (2311429)
Christoph Mayer (57204)
Sébastien Rigali (724082)
Navraj Pannu (10163763)
Jan Pieter Abrahams (1429531)
Lennart Schada von Borzyskowski (22683583)
Gilles P. van Wezel (7838948)
dc.date.none.fl_str_mv 2025-11-25T19:00:09Z
dc.identifier.none.fl_str_mv 10.1371/journal.pbio.3003514.s005
dc.relation.none.fl_str_mv https://figshare.com/articles/figure/Size-exclusion_chromatography_analysis_of_purified_NagS_/30715144
dc.rights.none.fl_str_mv CC BY 4.0
info:eu-repo/semantics/openAccess
dc.subject.none.fl_str_mv Biochemistry
Microbiology
Ecology
Developmental Biology
Inorganic Chemistry
Biological Sciences not elsewhere classified
controls nutrient signaling
also revealed 6
highlighted key residues
glcnac sensing requires
toxicity pathway dependent
6p deacetylase naga
novel glcnac 6
key role
substrate glcnac
novel enzyme
work uncovers
wall leads
unprecedented reaction
substrate mycelium
structural analogue
streptomycetaceae </
streptomyces </
revolves around
promiscuous activity
nature ’
n </
multicellular lifestyle
metabolic checkpoint
medicine makers
lytic dismantling
landmark event
hyphal cell
highly conserved
growth media
function analysis
clinical antibiotics
central metabolism
catalytic inhibitor
antibiotic production
active site
>- acetylglucosamine
6p dehydratase
dc.title.none.fl_str_mv Size-exclusion chromatography analysis of purified NagS.
dc.type.none.fl_str_mv Image
Figure
info:eu-repo/semantics/publishedVersion
image
description <p>Analytical gel-filtration chromatography was performed on a Superdex 200 10/300 GL column (Cytiva) equilibrated with buffer containing 20 mM HEPES pH 7.5, 300 mM NaCl, 5% glycerol, and 1 mM DTT. NagS was analyzed at two protein concentrations (35 μM and 70 μM). Elution volumes (V<sub>e</sub>) (<a href="http://www.plosbiology.org/article/info:doi/10.1371/journal.pbio.3003514#pbio.3003514.s021" target="_blank">S7 Table</a>) were compared to a molecular weight (Mw) calibration curve above generated using a Protein Standard Mix under identical buffer conditions. The calibration curve followed the equation V<sub>e</sub> = –1.525ln(Mw) + 20.659 (R² = 0.964). Note: NagS eluted at 14.45 ml, which corresponds to an estimated molecular weight of ~60.04 kDa according to the calibration curve equation. Given that the calculated molecular weight of a NagS-His₆ monomer is 28.29 kDa, these results indicate that NagS exists as a dimer in the tested buffer. The data underlying this Figure can be found in <a href="http://www.plosbiology.org/article/info:doi/10.1371/journal.pbio.3003514#pbio.3003514.s022" target="_blank">S1 Data</a>.</p> <p>(TIF)</p>
eu_rights_str_mv openAccess
id Manara_319440e7046ade2d183e05f4b12fea26
identifier_str_mv 10.1371/journal.pbio.3003514.s005
network_acronym_str Manara
network_name_str ManaraRepo
oai_identifier_str oai:figshare.com:article/30715144
publishDate 2025
repository.mail.fl_str_mv
repository.name.fl_str_mv
repository_id_str
rights_invalid_str_mv CC BY 4.0
spelling Size-exclusion chromatography analysis of purified NagS.Chao Li (145513)Mia Urem (22683580)Ioli Kotsogianni (9930187)Josephine Lau (20442343)Chao Du (288036)Somayah S. Elsayed (9192571)Nathaniel I. Martin (847378)Iain W. McNae (840777)Patrick Voskamp (2311429)Christoph Mayer (57204)Sébastien Rigali (724082)Navraj Pannu (10163763)Jan Pieter Abrahams (1429531)Lennart Schada von Borzyskowski (22683583)Gilles P. van Wezel (7838948)BiochemistryMicrobiologyEcologyDevelopmental BiologyInorganic ChemistryBiological Sciences not elsewhere classifiedcontrols nutrient signalingalso revealed 6highlighted key residuesglcnac sensing requirestoxicity pathway dependent6p deacetylase naganovel glcnac 6key rolesubstrate glcnacnovel enzymework uncoverswall leadsunprecedented reactionsubstrate myceliumstructural analoguestreptomycetaceae </streptomyces </revolves aroundpromiscuous activitynature ’n </multicellular lifestylemetabolic checkpointmedicine makerslytic dismantlinglandmark eventhyphal cellhighly conservedgrowth mediafunction analysisclinical antibioticscentral metabolismcatalytic inhibitorantibiotic productionactive site>- acetylglucosamine6p dehydratase<p>Analytical gel-filtration chromatography was performed on a Superdex 200 10/300 GL column (Cytiva) equilibrated with buffer containing 20 mM HEPES pH 7.5, 300 mM NaCl, 5% glycerol, and 1 mM DTT. NagS was analyzed at two protein concentrations (35 μM and 70 μM). Elution volumes (V<sub>e</sub>) (<a href="http://www.plosbiology.org/article/info:doi/10.1371/journal.pbio.3003514#pbio.3003514.s021" target="_blank">S7 Table</a>) were compared to a molecular weight (Mw) calibration curve above generated using a Protein Standard Mix under identical buffer conditions. The calibration curve followed the equation V<sub>e</sub> = –1.525ln(Mw) + 20.659 (R² = 0.964). Note: NagS eluted at 14.45 ml, which corresponds to an estimated molecular weight of ~60.04 kDa according to the calibration curve equation. Given that the calculated molecular weight of a NagS-His₆ monomer is 28.29 kDa, these results indicate that NagS exists as a dimer in the tested buffer. The data underlying this Figure can be found in <a href="http://www.plosbiology.org/article/info:doi/10.1371/journal.pbio.3003514#pbio.3003514.s022" target="_blank">S1 Data</a>.</p> <p>(TIF)</p>2025-11-25T19:00:09ZImageFigureinfo:eu-repo/semantics/publishedVersionimage10.1371/journal.pbio.3003514.s005https://figshare.com/articles/figure/Size-exclusion_chromatography_analysis_of_purified_NagS_/30715144CC BY 4.0info:eu-repo/semantics/openAccessoai:figshare.com:article/307151442025-11-25T19:00:09Z
spellingShingle Size-exclusion chromatography analysis of purified NagS.
Chao Li (145513)
Biochemistry
Microbiology
Ecology
Developmental Biology
Inorganic Chemistry
Biological Sciences not elsewhere classified
controls nutrient signaling
also revealed 6
highlighted key residues
glcnac sensing requires
toxicity pathway dependent
6p deacetylase naga
novel glcnac 6
key role
substrate glcnac
novel enzyme
work uncovers
wall leads
unprecedented reaction
substrate mycelium
structural analogue
streptomycetaceae </
streptomyces </
revolves around
promiscuous activity
nature ’
n </
multicellular lifestyle
metabolic checkpoint
medicine makers
lytic dismantling
landmark event
hyphal cell
highly conserved
growth media
function analysis
clinical antibiotics
central metabolism
catalytic inhibitor
antibiotic production
active site
>- acetylglucosamine
6p dehydratase
status_str publishedVersion
title Size-exclusion chromatography analysis of purified NagS.
title_full Size-exclusion chromatography analysis of purified NagS.
title_fullStr Size-exclusion chromatography analysis of purified NagS.
title_full_unstemmed Size-exclusion chromatography analysis of purified NagS.
title_short Size-exclusion chromatography analysis of purified NagS.
title_sort Size-exclusion chromatography analysis of purified NagS.
topic Biochemistry
Microbiology
Ecology
Developmental Biology
Inorganic Chemistry
Biological Sciences not elsewhere classified
controls nutrient signaling
also revealed 6
highlighted key residues
glcnac sensing requires
toxicity pathway dependent
6p deacetylase naga
novel glcnac 6
key role
substrate glcnac
novel enzyme
work uncovers
wall leads
unprecedented reaction
substrate mycelium
structural analogue
streptomycetaceae </
streptomyces </
revolves around
promiscuous activity
nature ’
n </
multicellular lifestyle
metabolic checkpoint
medicine makers
lytic dismantling
landmark event
hyphal cell
highly conserved
growth media
function analysis
clinical antibiotics
central metabolism
catalytic inhibitor
antibiotic production
active site
>- acetylglucosamine
6p dehydratase