Rational Optimization of Ammonium and Phosphonium Cations of Bifunctional Organoborane Catalysts for Copolymerization of Propylene Oxide with CO<sub>2</sub> to Afford Poly(propylene carbonate)
Ring-opening copolymerization (ROCOP) of CO<sub>2</sub> and propylene oxide (PO) is a challenging task due to its tendency to generate a polyether linkage and cyclic carbonate. Our group recently reported a series of mononuclear organoborane catalysts for the efficient ROCOP of CO<sub...
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2024
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