Mn-Catalyzed Regio- and Stereoselective C(sp3)–H Lactonization of Carboxylic Acids with H2O2

Recently, nonheme manganese complexes with bis-amino-bis-pyridylmethyl and structurally related ligands have been reported to efficiently catalyze the intramolecular C–H acyloxylation of readily available linear carboxylic (fatty) acids, directly converting thos...

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Bibliographic Details
Main Author:	Vladimir I. Kurganskiy (14198312) (author)
Other Authors:	Anna A. Bryliakova (10681563) (author), Alexander G. Medvedev (1517458) (author), Mikhail V. Shashkov (10681565) (author), Konstantin P. Bryliakov (1391833) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Inorganic Chemistry Plant Biology Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified synthetically useful yields structurally related ligands nonheme manganese complexes molecular mechanisms responsible lying quintet pes linear main chain general oxidation protocol dlpno – ccsd allows deliberately switching intramolecular carboxylate rebound >- amino -< 2 </ sub intramolecular 1 >- pyridylmethyl ee </ bis </ terminal oxidant stereoselective c spin crossing reaction selectivity reaction outcome proceed enantioselectively overall picture isotopic labeling formally consistent efficiently performed efficiently catalyze directly converting combined experimental catalyzed regio 1 hydroxylation )) data
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Mn-Catalyzed Regio- and Stereoselective C(sp<sup>3</sup>)–H Lactonization of Carboxylic Acids with H<sub>2</sub>O<sub>2</sub>

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