Reversible C–H Bond Activation of Unactivated Arenes by a Nickel-Silylene Complex

A nickel-silylene complex is shown to reversibly activate benzene via C–H bond activation at ambient temperature. The benzene C–H bond formally adds across the Ni–Si core to form a nickel-silyl complex with an H–Si–Ni–Ph linkage bearing a highly covalent Ni–Si bond (2.2363(6) Å). Dissolution of this...

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Bibliographic Details
Main Author:	Leon Gomm (21811882) (author)
Other Authors:	Hui Zhu (87035) (author), Gregor Schnakenburg (1393753) (author), Senada Nozinovic (2280559) (author), Stefan Grimme (1321575) (author), Connie C. Lu (1455736) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Cell Biology Cancer Science Policy Hematology Environmental Sciences not elsewhere classified Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified g ., toluene concerted oxidative addition arene initially forms neat arene solvent å ). unactivated arenes silylene complex silyl complex resultant hydride redox burden facile reversibility complete conversion ambient temperature 0 ),
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Reversible C–H Bond Activation of Unactivated Arenes by a Nickel-Silylene Complex

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