DataSheet1_Carbon fibers decorated with TiO2 nanoparticles for photocatalytic degradation of methylene blue dye.docx

<p>This report demonstrates the development of carbon fibers (CFs) decorated with TiO<sub>2</sub> nanoparticles (NPs) as an efficient photocatalyst for the photocatalytic degradation of methylene blue (MB) as a model dye. Carbon fibers were produced by carbonization of polyacryloni...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Pavan Kumar Chennam (16533206) (author)
مؤلفون آخرون: Marcela Sepúlveda (8307663) (author), Martina Rihova (19931409) (author), Mahnaz Alijani (15073876) (author), Martin Kachlík (19931412) (author), Raul Zazpe (4115110) (author), David Pavlinak (17295019) (author), Karel Maca (3045018) (author), Jan M. Macak (2497930) (author)
منشور في: 2024
الموضوعات:
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الوصف
الملخص:<p>This report demonstrates the development of carbon fibers (CFs) decorated with TiO<sub>2</sub> nanoparticles (NPs) as an efficient photocatalyst for the photocatalytic degradation of methylene blue (MB) as a model dye. Carbon fibers were produced by carbonization of polyacrylonitrile fibers, previously produced by centrifugal spinning. Subsequently, the CFs were decorated with TiO<sub>2</sub> NPs (CFs@TiO<sub>2</sub>) by tailored soaking protocol using aqueous TiCl<sub>4</sub> solution with different concentrations (0.025, 0.05, 0.1, and 0.2 M). SEM analyses revealed that soaking in TiCl<sub>4</sub> produced a smooth, conformal, continuous TiO<sub>2</sub> nanoparticulate coating with thickness increasing from 40.4 ± 21.2 to 257.9 ± 63.9 nm with increasing TiCl<sub>4</sub> concentration. X-ray diffraction and Raman spectroscopy confirmed the anatase nature of TiO<sub>2</sub>. Photocatalytic decomposition rates of MB were assessed under UV light illumination for all CFs@TiO<sub>2</sub> samples, and it was revealed that the lowest amount of TiO<sub>2</sub> NP on C yielded the highest rates. The synergistic interaction between CFs and TiO<sub>2</sub> NPs with a uniform morphology and a well-crystalline anatase structure, present in an optimal amount of fiber bodies, is the key reason for the remarkable photocatalytic performance. This work shows that C fibers decorated with an optimal amount of TiO<sub>2</sub> NPs have a great potential as an effective photocatalytic material.</p>