Air-Stable Copper(I) Borohydride for Carbon Disulfide Mitigation through Sustainable Hydride Transfer

Air-Stable Copper(I) Borohydride for Carbon Disulfide Mitigation through Sustainable Hydride Transfer

We report the synthesis and characterization of an air-stable copper(I) borohydride, [Cu(PNN)(μ-BH<sub>4</sub>)], stabilized by a koneramine-derived PNN ligand featuring mixed phosphorus and nitrogen donors. The ligand framework imparts high oxidation resistance, enabling the isolation o...

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Bibliographische Detailangaben
1. Verfasser: Archana Yadav (569783) (author)
Weitere Verfasser: Raja Angamuthu (582134) (author)
Veröffentlicht: 2025
Schlagworte:
Biophysics
Biochemistry
Ecology
Space Science
Environmental Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
sustainable organometallic strategy
sustainable hydride transfer
pnn )( μ
hydride transfer process
combining structural robustness
carbon disulfide mitigation
selective c –
3 </ sub
selective reactivity
work establishes
study highlights
stable copper
precious metals
pollutant activation
nitrogen donors
mild conditions
including cs
bisulfate derivatives
abundant metal
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