A Terminal Germanium Oxido Dianion by Structural Constraints

Terminal oxides of late transition and main group metal(loid)s are typically highly basic and intrinsically prone to oligomerization. Their isolation traditionally relied on stabilizing π-interactions with the metal, external Lewis acids, or hydrogen bonding. Here, we present an alternative strategy...

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主要作者:	Valentin D. Hannibal (19528901) (author)
其他作者:	Lutz Greb (1412410) (author)
出版:	2025
主題:	Biophysics Biochemistry Neuroscience Biotechnology Virology Computational Biology Chemical Sciences not elsewhere classified ≈ 34 ), significant lumo lowering reactivity studies identify le bel configuration isolation traditionally relied external lewis acids amido macrocyclic ligand typically highly basic geo ]< sup 2 –</ sup main group metal 2 </ sub highly polarized k </ </ sub van ’ transfer agent terminal oxide structural motif structural constraints structural constraint strong nucleophile state superbases stabilizing π stabilize terminal single bond nearly square molecular germanate late transition kind monomeric intrinsically prone hydrogen bonding fundamental importance findings highlight effective strategy double deprotonation brønsted superbase bond activation analyses reveal alternative strategy adduct affords >< sub
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A Terminal Germanium Oxido Dianion by Structural Constraints

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