Crystal and Molecular Structure of Manganese(II) Lapacholate, a Novel Polymeric Species Undergoing Temperature-Reversible Metal to Ligand Electron Transfer

Crystal and Molecular Structure of Manganese(II) Lapacholate, a Novel Polymeric Species Undergoing Temperature-Reversible Metal to Ligand Electron Transfer

Lapachol (2-hydroxy-3-(3-methyl-2-butenyl)-1,4-naphtoquinone) (HLap, C<sub>15</sub>H<sub>14</sub>O<sub>3</sub>) reacts with Mn<sup>2+</sup> producing a novel polymeric complex with formula: [Mn(Lap)<sub>2</sub>]<sub><i>n</i&g...

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Bibliographic Details
Main Author:	Francesco Caruso (201563) (author)
Other Authors:	Miguel A. Martínez (2379574) (author), Miriam Rossi (201573) (author), Alexander Goldberg (254010) (author), M. Elizabeth Chacón Villalba (2379568) (author), Pedro J. Aymonino (2379571) (author)
Published:	2009
Subjects:	Biochemistry Cell Biology Molecular Biology Biotechnology Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified thermogravimetric analysis C 15H carbonyl O 1 donor para oxygens theory study ortho oxygen semiquinonate action Lap ligands octahedral coordination sphere Lap metal complexes Molecular Structure electron transfer ligands chelate coordinative bond 300 K MnII species Mn contribution UV oxygen binding bidentate ligand IR Lap ligand room T
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