Tuning Triplet Exciton Pathways via Molecular Aggregation in a Family of Coordination Polymers

Molecular aggregation is the key factor in determining the triplet exciton pathways of room-temperature phosphorescence (RTP) materials; however, controlling different aggregation forms and understanding their synergistic effects remain challenging. In this work, we report three coordination polymer...

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主要作者:	Rui Feng (186408) (author)
其他作者:	Zi-Ying Li (8932241) (author), Shi-Shuang Huang (19751845) (author), Mei-Hui Yu (3355967) (author), Fengxia Wei (1411588) (author), Jingwei Hou (832762) (author), Wei Li (7081) (author), Xian-He Bu (1605673) (author)
出版:	2025
主題:	Biophysics Biochemistry Medicine Neuroscience Cancer Space Science Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified theoretical analysis demonstrate resolved emission spectroscopy pyridyl )- 1 pyridine dicarboxylate enhanced charge migration enabling distinct fluorescent differentiated orbital energies manipulating molecular aggregation associated optical properties staggered translational stacking x aggregation ): cofacial translational stacking aggregation ), cofacial 2 </ sub 2 </ b triplet exciton pathways 3 </ b pyc )< sub cofacial translational exciton pathways )< sub crossing stacking j aggregation aggregation modes triazine ), photochromic properties designated triplet crystal x (< b temperature phosphorescence separated photochromism ray diffraction key factor findings provide
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Tuning Triplet Exciton Pathways via Molecular Aggregation in a Family of Coordination Polymers

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