Chemical Activation of Frontal Ring-Opening Metathesis Polymerization

In this study, we present an innovative approach to frontal ring-opening metathesis polymerization (FROMP) through chemical activation. By locally concentrating Grubbs-type initiators, we accelerate exothermic polymerization at the activation site. Sufficient thermal energy initiates a polymerizatio...

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Bibliographic Details
Main Author:	Anna C. Cramblitt (6499682) (author)
Other Authors:	Justine E. Paul (9541135) (author), Tyler C. Price (21987509) (author), Parmeet Kaur (2068066) (author), Jeffrey S. Moore (1385685) (author), Nancy R. Sottos (1449940) (author), Jacob J. Lessard (5629013) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Neuroscience Physiology Biotechnology Evolutionary Biology Chemical Sciences not elsewhere classified Physical Sciences not elsewhere classified thermal energy generated locally concentrating grubbs external power sources composite materials using opening metathesis polymerization accelerate exothermic polymerization reduced initiator concentrations chemical activation enables chemical activation polymerization front initiator reactivity activation site various initiators type initiators transport solvent synchronized injection sample even relative reactivity limited environments innovative approach initiation location frontal ring enabling deployment demand production bulk resin accessible method
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Chemical Activation of Frontal Ring-Opening Metathesis Polymerization

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