Peptidyl Glycosyl Thiols and Disulfides for Enantioselective Hydrogen Atom Transfer (HAT) and Thiyl Radical Catalysis
A novel class of peptidyl glycosyl disulfide and thiol catalysts is developed. The thiols are found to catalyze enantioselective olefin hydrosilylation up to 5:95 er. The disulfide catalysts are competent in an enantioselective thiyl-catalyzed cycloaddition reaction, yielding product with complement...
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2025
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