Photoresponsive Organic CagesComputationally Inspired Discovery of Azobenzene-Derived Organic Cages

Photoresponsive Organic CagesComputationally Inspired Discovery of Azobenzene-Derived Organic Cages

The incorporation of photoresponsive groups into porous materials is attractive as it offers potential advantages in controlling the pore size and selectivity to guest molecules. A combination of computational modeling and experiment resulted in the synthesis of two azobenzene-derived organic cages...

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محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Michael C. Brand (19929021) (author)
مؤلفون آخرون: Hamish G. Trowell (19929024) (author), James T. Pegg (5557214) (author), Jake L. Greenfield (1650277) (author), Magdalena Odaybat (13948512) (author), Marc A. Little (1396594) (author), Peter R. Haycock (1758946) (author), Gokay Avci (5216444) (author), Nicola Rankin (19929027) (author), Matthew J. Fuchter (448476) (author), Kim E. Jelfs (1297440) (author), Andrew I. Cooper (1297431) (author), Rebecca L. Greenaway (5131307) (author)
منشور في: 2024
الموضوعات:
Biochemistry
Genetics
Molecular Biology
Neuroscience
Pharmacology
Evolutionary Biology
Inorganic Chemistry
Biological Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
uv – vis
using either ditopic
tritopic aldehyde forms
ditopic aldehyde forms
detailed kinetic analysis
corresponding intrinsic cavities
h nmr spectroscopy
fold imine condensation
derived organic cages
cages underwent photoisomerization
offers potential advantages
building blocks identified
overall thermal half
1 </ sup
different cage species
thermal isomerization
fold isomerization
110 h
zzz </
ezz </
eez </
cis </
work demonstrates
therefore capable
relative energies
porous materials
pore size
photoswitching properties
photoswitching behavior
photostationary state
photoresponsive materials
photoresponsive groups
metastable isomers
isomeric state
guest molecules
experiment resulted
contrasting effects
computational screen
computational modeling
cage via
>- isomer
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