Photoresponsive Organic CagesComputationally Inspired Discovery of Azobenzene-Derived Organic Cages

The incorporation of photoresponsive groups into porous materials is attractive as it offers potential advantages in controlling the pore size and selectivity to guest molecules. A combination of computational modeling and experiment resulted in the synthesis of two azobenzene-derived organic cages...

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Bibliographic Details
Main Author:	Michael C. Brand (19929021) (author)
Other Authors:	Hamish G. Trowell (19929024) (author), James T. Pegg (5557214) (author), Jake L. Greenfield (1650277) (author), Magdalena Odaybat (13948512) (author), Marc A. Little (1396594) (author), Peter R. Haycock (1758946) (author), Gokay Avci (5216444) (author), Nicola Rankin (19929027) (author), Matthew J. Fuchter (448476) (author), Kim E. Jelfs (1297440) (author), Andrew I. Cooper (1297431) (author), Rebecca L. Greenaway (5131307) (author)
Published:	2024
Subjects:	Biochemistry Genetics Molecular Biology Neuroscience Pharmacology Evolutionary Biology Inorganic Chemistry Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified uv – vis using either ditopic tritopic aldehyde forms ditopic aldehyde forms detailed kinetic analysis corresponding intrinsic cavities h nmr spectroscopy fold imine condensation derived organic cages cages underwent photoisomerization offers potential advantages building blocks identified overall thermal half 1 </ sup different cage species thermal isomerization fold isomerization 110 h zzz </ ezz </ eez </ cis </ work demonstrates therefore capable relative energies porous materials pore size photoswitching properties photoswitching behavior photostationary state photoresponsive materials photoresponsive groups metastable isomers isomeric state guest molecules experiment resulted contrasting effects computational screen computational modeling cage via >- isomer
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Photoresponsive Organic CagesComputationally Inspired Discovery of Azobenzene-Derived Organic Cages

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