Thiourea-Promoted Controllable Interlocked Polymerization in Cocrystals of <i>N</i>‑Thiocarboxyanhydrides

Poly(amino acid)s, renowned for their biodegradability and structural versatility, are widely used in biomedical applications. While <i>N</i>-carboxyanhydride (NCA) ring-opening polymerization (ROP) has enabled polypeptide synthesis, challenges persist in controlling β-branched amino aci...

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Bibliographic Details
Main Author:	Chuanmeng Tang (22653847) (author)
Other Authors:	Jiahao Liu (2398594) (author), Zhuoyuan Zhang (6628634) (author), Tianwen Bai (3903637) (author)
Published:	2025
Subjects:	Biophysics Biochemistry Medicine Pharmacology Biotechnology Developmental Biology Space Science Chemical Sciences not elsewhere classified Information Systems not elsewhere classified superior hydrolytic stability strategy yields high addressing longstanding limitations >‑ thiocarboxyanhydrides poly enabled polypeptide synthesis catalyzed rop system polypeptide synthesis >- thiocarboxyanhydrides work broadens widely used weight polyvaline valine due structural versatility order kinetics opening polymerization ntas ), n </ monomer choice mild conditions maintains zero low reactivity k </ functional biomaterials controlling β challenges persist biomedical applications best catalyst amino acid >< sub >- carboxyanhydride
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Thiourea-Promoted Controllable Interlocked Polymerization in Cocrystals of <i>N</i>‑Thiocarboxyanhydrides

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